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atropurpuran

National Institutes of Health

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Diterpenes

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2016
2016
π(4)s + π(2)s Cycloaddition of Spiroepoxycyclohexa-2,4-dienone, Radical Cyclization, and Oxidation-Aldol-Oxidation Cascade: Synthesis of BCDE Ring of Atropurpuran.
Synthesis of a tetracyclic ring system (BCDE) of atropurpuran is described. Oxidative dearomatization, cycloaddition of… 
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