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aromatic amine dehydrogenase

National Institutes of Health

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Oxidoreductases Acting on CH-NH Group Donors
aralkylamine dehydrogenase activity

Papers overview

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2008
2008
The enzyme aromatic amine dehydrogenase induces a substrate conformation crucial for promoting vibration that significantly reduces the effective potential energy barrier to proton transfer
The role of promoting vibrations in enzymic reactions involving hydrogen tunnelling is contentious. While models incorporating… 
2008
2008
Catalysis by the isolated tryptophan tryptophylquinone-containing subunit of aromatic amine dehydrogenase is distinct from native enzyme and synthetic model compounds and allows further probing of…
Para-substituted benzylamines are poor reactivity probes for structure-reactivity studies with TTQ-dependent aromatic amine… 
2008
2008
Driving Force Analysis of Proton Tunnelling Across a Reactivity Series for an Enzyme‐Substrate Complex
Quantitative structure‐activity relationships are widely used to probe CH bond breakage by quinoprotein enzymes.[1–4] However… 
2007
2007
Isotope effects reveal that para-substituted benzylamines are poor reactivity probes of the quinoprotein mechanism for aromatic amine dehydrogenase.
Structure-activity correlations have been employed previously in the mechanistic interpretation of TTQ-dependent amine… 
2006
2006
Atomic Level Insight into the Oxidative Half-reaction of Aromatic Amine Dehydrogenase*
The quinoprotein aromatic amine dehydrogenase (AADH) uses a covalently bound tryptophan tryptophylquinone (TTQ) cofactor to… 
2005
2005
Tryptophan tryptophylquinone cofactor biogenesis in the aromatic amine dehydrogenase of Alcaligenes faecalis
The heterologous expression of tryptophan trytophylquinone (TTQ)‐dependent aromatic amine dehydrogenase (AADH) has been achieved… 
1999
1999
Gated and Ungated Electron Transfer Reactions from Aromatic Amine Dehydrogenase to Azurin*
Interprotein electron transfer (ET) occurs between the tryptophan tryptophylquinone (TTQ) prosthetic group of aromatic amine… 
1998
1998
Identification of reaction products and intermediates of aromatic-amine dehydrogenase by 15N and 13C NMR.
13C- and 15N-NMR studies of the reaction of aromatic amine dehydrogenase (AADH) with methylamine demonstrated that the products… 
1998
1998
Kinetic and chemical mechanisms for the effects of univalent cations on the spectral properties of aromatic amine dehydrogenase.
Univalent cations and pH influence the UV-visible absorption spectrum of the tryptophan tryptophylquinone (TTQ) enzyme, aromatic… 
1995
1995
Spectroscopic Evidence for a Common Electron Transfer Pathway for Two Tryptophan Tryptophylquinone Enzymes (*)
Aromatic amine dehydrogenase (AADH) and methylamine dehydrogenase (MADH) are the only two enzymes known to use the cofactor… 
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