aigialomycin D
National Institutes of Health
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Many metabolites produced by various microorganisms
have proven their usefulness in the area concerning human health. However…
kinase inhibitors amongst the RALs have revived interest in this family of natural products. Interestingly, target proteins of…
The total synthesis of aigialomycin D, without the need for phenol protection, was carried out using the C-acylation of a keto…
The total synthesis of aigialomycin D was carried out using a nickel-catalyzed ynal macrocyclization as a key step. This key step…
In 2002 a new family of 14-membered resorcylic macrolides, the aigialomycins, were isolated from the mangrove fungus Aigialus…
On solid ground: Despite no obvious resemblance to adenosine analogues, the family of resorcyclic macrolides contains a high…
[reaction: see text] The first total synthesis of resorcinylic macrolide aigialomycin D was described. The resorcinylic moiety…