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acetylacetone-cleaving enzyme activity

Known as: acetylacetone dioxygenase activity, acetylacetone:oxygen oxidoreductase activity, diketone cleaving dioxygenase activity 
Catalysis of the reaction: pentane-2,4-dione + O2 = acetate + 2-oxopropanal. [EC:1.13.11.50]
National Institutes of Health

Papers overview

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2014
2014
Three new mononuclear copper(II) complexes, [Cu(L2)](2+) (1), [Cu(acac)(L)](+) (2), and [Cu(acac-Cl)(L)](+) (3) (L = 2-(4… 
2012
2012
This study elucidates the role of the protein structure in the catalysis of β-diketone cleavage at the three-histidine metal… 
2011
2011
A series of high-spin iron(II) β-diketonato complexes have been prepared and characterized with the intent of modeling the… 
2010
2010
The oxygen activating mononuclear non-heme ferrous enzymes catalyze a diverse range of chemistry yet typically maintain a common… 
2008
2008
A novel enantioselective total synthesis of the oral contraceptive desogestrel (2) is described, in which the tetracyclic steroid… 
2004
2004
Acinetobacter johnsonii acetylacetone dioxygenase (Dke1) is a non-heme Fe(II)-dependent dioxygenase that cleaves C-C bonds in… 
Highly Cited
2003
Highly Cited
2003
The toxicity of acetylacetone has been demonstrated in various studies. Little is known, however, about metabolic pathways for… 
Highly Cited
1979
Highly Cited
1979
Isolated cells labelled by means of 111 In-oxine (8-hydroxyquinoline) have been found clinically acceptable for the diagnosis of…