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acetylacetone-cleaving enzyme activity
Known as:
acetylacetone dioxygenase activity
, acetylacetone:oxygen oxidoreductase activity
, diketone cleaving dioxygenase activity
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Catalysis of the reaction: pentane-2,4-dione + O2 = acetate + 2-oxopropanal. [EC:1.13.11.50]
National Institutes of Health
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Related topics
Related topics
2 relations
acetylacetone-cleaving enzyme
diketone cleaving enzyme
Papers overview
Semantic Scholar uses AI to extract papers important to this topic.
2015
2015
Enantioselective Nazarov Cyclization Catalyzed by a Cinchona Alkaloid Derivative.
Yu‐Wen Huang
,
A. Frontier
Tetrahedron Letters
2015
Corpus ID: 11286673
2014
2014
Synthesis, characterization, DNA binding, cleavage activity and cytotoxicity of copper(II) complexes.
Mei-Jin Li
,
T. Lan
,
+4 authors
Guo-nan Chen
Dalton Transactions
2014
Corpus ID: 23778701
Three new mononuclear copper(II) complexes, [Cu(L2)](2+) (1), [Cu(acac)(L)](+) (2), and [Cu(acac-Cl)(L)](+) (3) (L = 2-(4…
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2012
2012
Dke1—structure, dynamics, and function: a theoretical and experimental study elucidating the role of the binding site shape and the hydrogen-bonding network in catalysis
H. Brkić
,
Daniela Buongiorno
,
M. Ramek
,
G. Straganz
,
S. Tomić
JBIC Journal of Biological Inorganic Chemistry
2012
Corpus ID: 14223790
This study elucidates the role of the protein structure in the catalysis of β-diketone cleavage at the three-histidine metal…
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2011
2011
Synthesis and characterization of Fe(II) β-diketonato complexes with relevance to acetylacetone dioxygenase: insights into the electronic properties of the 3-histidine facial triad.
Heaweon Park
,
J. Baus
,
S. Lindeman
,
Adam T. Fiedler
Inorganic Chemistry
2011
Corpus ID: 31899046
A series of high-spin iron(II) β-diketonato complexes have been prepared and characterized with the intent of modeling the…
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2010
2010
The three-his triad in Dke1: comparisons to the classical facial triad.
Adrienne R. Diebold
,
M. Neidig
,
G. Moran
,
G. Straganz
,
E. Solomon
Biochemistry
2010
Corpus ID: 11295589
The oxygen activating mononuclear non-heme ferrous enzymes catalyze a diverse range of chemistry yet typically maintain a common…
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2008
2008
Enantioselective total synthesis of the oral contraceptive desogestrel by a double Heck reaction.
L. Tietze
,
Ilga K Krimmelbein
Chemistry
2008
Corpus ID: 26885746
A novel enantioselective total synthesis of the oral contraceptive desogestrel (2) is described, in which the tetracyclic steroid…
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2004
2004
Electronic substituent effects on the cleavage specificity of a non-heme Fe(2+)-dependent beta-diketone dioxygenase and their mechanistic implications.
G. Straganz
,
H. Hofer
,
W. Steiner
,
B. Nidetzky
Journal of the American Chemical Society
2004
Corpus ID: 23055830
Acinetobacter johnsonii acetylacetone dioxygenase (Dke1) is a non-heme Fe(II)-dependent dioxygenase that cleaves C-C bonds in…
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Highly Cited
2003
Highly Cited
2003
Acetylacetone-cleaving enzyme Dke1: a novel C-C-bond-cleaving enzyme from Acinetobacter johnsonii.
G. Straganz
,
A. Glieder
,
L. Brecker
,
D. Ribbons
,
W. Steiner
Biochemical Journal
2003
Corpus ID: 17407678
The toxicity of acetylacetone has been demonstrated in various studies. Little is known, however, about metabolic pathways for…
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2000
2000
Separation of divalent transition metal beta-diketonates and their adducts by supercritical fluid chromatography.
Y. Lin
,
H. Wu
,
C. Wai
,
N. Smart
Talanta: The International Journal of Pure and…
2000
Corpus ID: 45039200
Highly Cited
1979
Highly Cited
1979
Simplified cell labelling with indium-111 acetylacetone.
H. Sinn
,
D. Silvester
British Journal of Radiology
1979
Corpus ID: 32678285
Isolated cells labelled by means of 111 In-oxine (8-hydroxyquinoline) have been found clinically acceptable for the diagnosis of…
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