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Malonates

Known as: Malonates [Chemical/Ingredient] 
Derivatives of malonic acid (the structural formula CH2(COOH)2), including its salts and esters.
National Institutes of Health

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2,2-dimethyl-n-benzylmalonamide2-benzylmalonate2-n-butylmalonate2-nitrobenzoylaminomalonate
In Bloodagonistsantagonists & inhibitorsaspects of radiation effects

Papers overview

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Highly Cited
2012
Highly Cited
2012
Metal-free hydrogenation of electron-poor allenes and alkenes.
An equimolar catalytic mixture of DABCO and tris(pentafluorophenyl)borane is successfully employed in the process. 
Highly Cited
2010
Highly Cited
2010
Understanding selectivity of hard and soft metal cations within biological systems using the subvalence concept. I. Application to blood coagulation: direct cation-protein electronic effects vs…
Following a previous study by de Courcy et al. ((2009) Interdiscip. Sci. Comput. Life Sci. 1, 55-60), we demonstrate in this… 
Review
2009
Review
2009
Asymmetric organocatalysis by chiral Brønsted bases: implications and applications.
Chiral, metal-free Brønsted bases have been demonstrated capable of catalyzing several types of C-C and C-X bond-forming… 
Highly Cited
2007
Highly Cited
2007
Chiral calcium complexes as brønsted base catalysts for asymmetric addition of α-amino acid derivatives to α,β-unsaturated carbonyl compounds
A novel catalyst system based on complexes of calcium which promote the catalytic asymmetric 1,4-addition reactions and [3+2… 
Highly Cited
2006
Highly Cited
2006
The Mannich reaction of malonates with simple imines catalyzed by bifunctional cinchona alkaloids: enantioselective synthesis of beta-amino acids.
We describe the first efficient, direct asymmetric Mannich reactions with malonates and N-Boc aryl and alkyl imines by… 
Highly Cited
2006
Highly Cited
2006
Asymmetric organocatalytic conjugate addition of malonates to enones using a proline tetrazole catalyst.
5-Pyrrolidin-2-yltetrazole performs as a useful organocatalyst for the asymmetric addition of malonates to a range of enones… 
Highly Cited
2004
Highly Cited
2004
Controllable enantioselective Friedel-Crafts reaction between indoles and alkylidene malonates catalyzed by pseudo-C3-symmetric trisoxazoline copperII complexes.
Pseudo-C(3)-symmetric trisoxazoline copper(II) complexes prove to be excellent catalysts in the Friedel-Crafts alkylation of… 
Highly Cited
2002
Highly Cited
2002
Sidearm effect: improvement of the enantiomeric excess in the asymmetric Michael addition of indoles to alkylidene malonates.
A pseudo-C3-trisoxazoline was designed and synthesized. The improvement of the traditional bisoxazoline into a novel… 
Highly Cited
2000
Highly Cited
2000
Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2-Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate…
C2-symmetric bis(oxazoline)−Cu(II) complexes 1 catalyze the Mukaiyama Michael reaction of alkylidene malonates and enolsilanes… 
Highly Cited
1999
Highly Cited
1999
Approaches to catalyst discovery. New carbon–heteroatom and carbon–carbon bond formation
Studies on the palladium-catalyzed formation of aryl amines, aryl ethers and a-aryl carbonyl compounds from aryl halides are… 
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