Imidates
National Institutes of Health
Papers overview
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A direct and practical metal-free N-H phosphorylation has been achieved via the TBHP/NH4I-mediated cross-dehydrogenative coupling…
Cobalt-catalyzed C-H allylation reactions of NH-free benzimidates using vinylcyclopropanes or allyl carbonate are reported. The…
The unique electronic reactivity of imidates has been recently exploited for the syntheses of diverse classes of N-heterocycles…
Previously we communicated 3,3-difluoroxindole (HOFox) - mediated glycosylations wherein 3,3-difluoro-3H-indol-2-yl (OFox…
The development of the first highly active enantioselective catalyst for the aza-Claisen rearrangement of Z-configured allylic…
This paper expands on the scope and utility of the temporary conversion of N-acetyl groups to alkyl imidates when attempting to…
A highly enantioselective and diastereoselective Claisen rearrangement of N-arylimidates derived from an axially chiral…
Methyl 1-beta-D-ribofuranosyl-1,2,4-triazole-3-carboximidate (4) and ethyl 1-beta-D-ribofuranosyl-1,2,4-triazole-3-carboxamidate…