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Imidates

National Institutes of Health

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Imidoesters

Papers overview

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2017
2017
OFox imidates as versatile glycosyl donors for chemical glycosylation.
Previously we communicated 3,3-difluoroxindole (HOFox) - mediated glycosylations wherein 3,3-difluoro-3H-indol-2-yl (OFox… 
2017
2017
4-Diazoisochroman-3-imines: A Class of Metal Carbene Precursors for the Synthesis of Isochromene Derivatives.
4-Diazoisochroman-3-imines were investigated for their synthetic applications as a new class of metal carbene precursors. Under… 
2017
2017
S-Benzimidazolyl (SBiz) Imidates as a Platform for Oligosaccharide Synthesis via Active-Latent, Armed-Disarmed, Selective, and Orthogonal Activations.
This article describes the development of S-benzimidazolyl (SBiz) imidates as versatile building blocks for oligosaccharide… 
Highly Cited
2008
Highly Cited
2008
Synthesis of nearly enantiopure allylic amines by aza-Claisen rearrangement of Z-configured allylic trifluoroacetimidates catalyzed by highly active ferrocenylbispalladacycles.
The development of the first highly active enantioselective catalyst for the aza-Claisen rearrangement of Z-configured allylic… 
2008
2008
Convenient temporary methyl imidate protection of N-acetylglucosamine and glycosylation at O-4.
This paper expands on the scope and utility of the temporary conversion of N-acetyl groups to alkyl imidates when attempting to… 
2004
2004
One-pot preparation and activation of glycosyl trichloroacetimidates: operationally simple glycosylation induced by combined use of solid-supported, reactivity-opposing reagents
1997
1997
Highly Enantioselective Claisen Rearrangement of Imidates Derived from Primary Allyl Alcohols.
A highly enantioselective and diastereoselective Claisen rearrangement of N-arylimidates derived from an axially chiral… 
Highly Cited
1994
Highly Cited
1994
Thermostabilized chemical derivatives of horseradish peroxidase.
1989
1989
Synthesis and antitumor activity of ribavirin imidates. A new facile synthesis of ribavirin amidine (1-beta-D-ribofuranosyl-1,2,4-triazole-3-carboxamidine hydrochloride).
Methyl 1-beta-D-ribofuranosyl-1,2,4-triazole-3-carboximidate (4) and ethyl 1-beta-D-ribofuranosyl-1,2,4-triazole-3-carboxamidate… 
1967
1967
Studies on ketene and its derivatives. XVII. Reaction of diketene with imidates.
Reactions of diketene with iminothers such as benziminoethylether and phenacetiminoethylether were investigated. Refluxing of… 
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