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4-Hydroxymandelate

 
National Institutes of Health

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2018
2018
Engineering of hydroxymandelate synthases and the aromatic amino acid pathway enables de novo biosynthesis of mandelic and 4-hydroxymandelic acid with Saccharomyces cerevisiae.
Mandelic acid (MA) and 4-hydroxymandelic acid (HMA) are valuable specialty chemicals used as precursors for flavors as well as… Expand
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2015
2015
Functional Exchangeability of Oxidase and Dehydrogenase Reactions in the Biosynthesis of Hydroxyphenylglycine, a Nonribosomal Peptide Building Block.
A key problem in the engineering of pathways for the production of pharmaceutical compounds is the limited diversity of… Expand
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2012
2012
Mechanism of benzylic hydroxylation by 4-hydroxymandelate synthase. A computational study.
Hydroxymandelate synthase (HMS) and 4-hydroxyphenylpyruvate dioxygenase (HPPD) are highly related enzymes using the same… Expand
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2012
2012
4-Hydroxyphenylglycine biosynthesis in Herpetosiphon aurantiacus: a case of gene duplication and catalytic divergence
The nonproteinogenic amino acid 4-hydroxyphenylglycine (HPG) arises from the diversion of the tyrosine degradation pathway into… Expand
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2011
2011
A public resource for metabolic pathway mapping of Aspergillus fumigatus Af293.
Our understanding of the human pathogenic fungus Aspergillus fumigatus has recently benefitted from much work at the genomics… Expand
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2008
2008
Two roads diverged: the structure of hydroxymandelate synthase from Amycolatopsis orientalis in complex with 4-hydroxymandelate.
The crystal structure of the hydroxymandelate synthase (HMS).Co2+.hydroxymandelate (HMA) complex determined to a resolution of 2… Expand
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2004
2004
4-Hydroxyphenylpyruvate dioxygenase: a hybrid density functional study of the catalytic reaction mechanism.
Density functional calculations using the B3LYP functional has been used to study the reaction mechanism of 4… Expand
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Highly Cited
2002
Highly Cited
2002
Structure, biosynthetic origin, and engineered biosynthesis of calcium-dependent antibiotics from Streptomyces coelicolor.
The calcium-dependent antibiotic (CDA), from Streptomyces coelicolor, is an acidic lipopeptide comprising an N-terminal 2,3… Expand
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1989
1989
Degradation of mandelate and 4-hydroxymandelate by Rhizobium leguminosarum biovar trifolii TA1
Rhizobium leguminosarum biovar trifolii TA1 grows on 4-hydroxymandelate and enzymes involved in its catabolism are inducible… Expand
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1976
1976
Metabolism of DL-(+/-)-phenylalanine by Aspergillus niger.
A fungus capable of degrading DL-phenylalanine was isolated from the soil and identified as Aspergillus niger. It was found to… Expand
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