1,2-azaborine

The BN analogue of ortho-benzyne, 1,2-azaborine, is generated by flash vacuum pyrolysis, trapped under cryogenic conditions, and… Expand

The first general late-stage functionalization of monocyclic 1,2-azaborines at the C(6) position is described. Ir-catalyzed C-H… Expand

Thermolysis of 9-azido-9-borafluorene in heptane solution produces the tetramer of a BN-phenanthryne. The isolation of the self… Expand

The reaction between trimethylsilyl azide and pentaphenylborole was recently shown to produce the corresponding 1,2-azaborine… Expand

The protecting group-free synthesis of a versatile 1,2-azaborine synthon 5 is described. Previously inaccessible 1,2-azaborine… Expand

A Sn-phony in B! BN isosteres of biphenyl compounds are prepared through Rh-catalyzed cross-coupling between 2-chloro-1,2… Expand

Could go either way: the addition of nucleophiles to the parent 1,2-dihydro-1,2-azaborine and subsequent quenching with an… Expand

1,2-Dihydro-1,2-azaborine is a six-membered aromatic heterocycle that is isoelectronic with benzene through the replacement of a… Expand

The element boron has not received much attention in biomedical applications compared to its periodic table neighbors carbon… Expand

Benzene (c-C6H6) is arguably one of the most fundamentally significant small molecules in chemistry. First discovered by Faraday… Expand