Thermal studies on Li(CH3CN)4PF6 and Li(C4H10O2)2PF6 complexes by the TG–DTA–MS and DSC

@article{Zhong2018ThermalSO,
  title={Thermal studies on Li(CH3CN)4PF6 and Li(C4H10O2)2PF6 complexes by the TG–DTA–MS and DSC},
  author={Yanjun Zhong and Xuecong Li and Zhanyong Gu and Xinlong Wang and Lin Yang and Xiushan Yang and Zhiye Zhang and Benhe Zhong},
  journal={Journal of Thermal Analysis and Calorimetry},
  year={2018},
  volume={131},
  pages={1287-1293},
  url={https://api.semanticscholar.org/CorpusID:104000302}
}
Li(CH3CN)4PF6 and Li(C4H10O2)2PF6 complexes are important intermediates created in the synthetic process of high-purity LiPF6 electrolyte via transformation method. The thermal decomposition behavior of as-prepared Li(CH3CN)4PF6 and Li(C4H10O2)2PF6 crystals in pure nitrogen atmosphere has been studied by means of thermogravimetric–differential thermal analysis coupled with mass spectrometry (TG–DTA–MS). Results suggest that the decomposition of Li(CH3CN)4PF6 complex can be roughly divided into… 
View on Springer
1 Citation

One Citation

Hermetic thermal behaviors and specific heat capacities of bis(aminofurazano)furazan and bis(nitrofurazano)furazan

Thermal behaviors of bis(aminofurazano)furazan (BAFF) and bis(nitrofurazano)furazan (BNFF) were studied by the differential scanning calorimetry (DSC) method with a special hermetic high-pressure…

23 References

Thermal decomposition of ammonium molybdates

The thermal behavior of ammonium molybdates, i.e., (NH4)6Mo7O24·4H2O (1) and (NH4)2MoO4 (2), was studied in inert (N2) and oxidizing (air) atmospheres by TG/DTA-MS, XRD, FTIR and SEM. The thermal…

Preparation and Characterization of a New Type Lithium Hexafluorophosphate Complex

In this paper, a new type lithium hexafluorophosphate (LiPF6) complex was prepared with a new method using phosphorus pentachlorine (PCl5), lithium fluoride (LiF) and 1,2-dimethoxyethane (C4H10O2).…

Kinetics analysis of thermal decomposition of ammonium dinitramide (ADN)

Kinetics analyses were performed on the thermal decomposition of ammonium dinitramide (ADN) using thermogravimetry-differential thermal analysis–mass spectrometry–infrared spectroscopy…

Thermal stability of lithium-ion battery electrolytes

Synthesis and characterization of tetraacetonitrilolithiumhexafluorophosphate crystal

Thermal Stability of LiPF6 Salt and Li-ion Battery Electrolytes Containing LiPF6

Thermal behavior and decomposition kinetics of six electrolyte salts by thermal analysis

On the thermal stability of LiPF6

Effects of acetonitrile and 1,2-dimethoxyethane on the conductivity of electrolyte in Li-ion battery

The influences of AN and DME on the conductivity of the LiPF6 electrolytes were researched in this paper.The results showed that the conductivity was enhanced with the increasing content of AN in the…

Thermal decomposition mechanism of ammonium nitrate and potassium chloride mixtures

The thermal decomposition of ammonium nitrate (AN) and potassium chloride (KCl) mixtures was investigated. The thermal properties were studied using differential scanning calorimetry (DSC), and the…