• DOI:10.1039/C39810000455
• Corpus ID: 96119922

Synthesis and X-ray crystal structure of 1,5-bis(acetoxymethyl)-tricyclo[2.1.0.02,5]pentan-3-one

@article{Irngartinger1981SynthesisAX,
  title={Synthesis and X-ray crystal structure of 1,5-bis(acetoxymethyl)-tricyclo[2.1.0.02,5]pentan-3-one},
  author={Hermann Irngartinger and Annette Goldmann and Raymond Schappert and Philip Garner and Paul. Dowd},
  journal={Journal of The Chemical Society, Chemical Communications},
  year={1981},
  pages={455-456},
  url={https://api.semanticscholar.org/CorpusID:96119922}
}

• H. Irngartinger, A. Goldmann, +2 authors P. Dowd
• Published 1981
• Chemistry
• Journal of The Chemical Society, Chemical Communications

1,5-Bis(acetoxymethyl)tricyclo[2·1.0·02,5] pentan-3-one (1) has been synthesized from 1,2-bis(acetoxymethyl)-3-diazoacetylcyclopropene by dirhodium tetra-acetate-catalysed intramolecular addition of the diazoketone to the cyclopropene double bond; an X-ray crystal structure determination of (1) reveals an extremely short bridging carbon-carbon bond. 

1,5-Bis(acetoxymethyl)tricyclo[2·1.0·02,5] pentan-3-one (1) has been synthesized from 1,2-bis(acetoxymethyl)-3-diazoacetylcyclopropene by dirhodium tetra-acetate-catalysed intramolecular addition of the diazoketone to the cyclopropene double bond; an X-ray crystal structure determination of (1) reveals an extremely short bridging carbon-carbon bond.