Remote-Raman Spectroscopy at Intermediate Ranges Using Low-Power cw Lasers
@article{Angel1992RemoteRamanSA, title={Remote-Raman Spectroscopy at Intermediate Ranges Using Low-Power cw Lasers}, author={Stanley M. Angel and Thomas J. Kulp and Thomas M. Vess}, journal={Applied Spectroscopy}, year={1992}, volume={46}, pages={1085 - 1091}, url={https://api.semanticscholar.org/CorpusID:95937544} }
A portable Raman system is described that has been developed for line-of-site spectral measurements of remotely located samples at intermediate ranges. Raman spectra were measured at distances up to 20 m with the use of a 40-mm-diameter collection optic (f/500) and at 16.7 m with a 22-mm-diameter collection optic (f/750). In all cases, low-power cw lasers were used with powers ranging from 23 to 100 mW. The system consists of a small f/4 image-corrected spectrograph with a liquid-nitrogen…
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32 References
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- 1990
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- 1987
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- 1988
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- 1977
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The several advantages of Raman lidar for remote measurements of stationary source emissions were quantitatively evaluated using a calibration tank at a distance of 300 m at night to assess the seriousness of induced fluorescence from plume aerosols.
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- 1983
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