Defect-Engineered Metal–Organic Frameworks: A Thorough Characterization of Active Sites Using CO as a Probe Molecule

@article{Wang2020DefectEngineeredMF,
  title={Defect-Engineered Metal–Organic Frameworks: A Thorough Characterization of Active Sites Using CO as a Probe Molecule},
  author={Junjun Wang and Weijia Wang and Zhiying Fan and Shuang Chen and Alexei Nefedov and Stefan Heissler and Roland A. Fischer and Christof W{\"o}ll and Yuemin Wang},
  journal={The Journal of Physical Chemistry C},
  year={2020},
  url={https://api.semanticscholar.org/CorpusID:234152665}
}
Defect engineering (DE) has been recognized as a powerful approach to tune the structural, optical, and chemical properties of metal–organic framework (MOF) materials. Here, a detailed characteriza... 
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13 Citations

13 Citations

Defect-Engineered Metal − Organic Frameworks: A Thorough Characterization of Active Sites Using CO as a Probe Molecule

: Defect engineering (DE) has been recognized as a powerful approach to tune the structural, optical, and chemical properties of metal − organic framework (MOF) materials. Here, a detailed…

Exploring Defect-Engineered Metal–Organic Frameworks with 1,2,4-Triazolyl Isophthalate and Benzoate Linkers

Synthesis and characterization of DEMOFs (defect-engineered metal–organic frameworks) with coordinatively unsaturated sites (CUSs) for gas adsorption, catalysis, and separation are reported. We use…

Catching the Reversible Formation and Reactivity of Surface Defective Sites in Metal–Organic Frameworks: An Operando Ambient Pressure-NEXAFS Investigation

In this work, we apply for the first time ambient pressure operando soft X-ray absorption spectroscopy (XAS) to investigate the location, structural properties, and reactivity of the defective sites…

Defects engineering simultaneously enhances activity and recyclability of MOFs in selective hydrogenation of biomass

The development of synthetic methodologies towards enhanced performance in biomass conversion is desirable due to the growing energy demand. Here we design two types of Ru impregnated MIL-100-Cr…

Layer-by-layer assembly of metal-organic framework thin films: Fabrication and advanced applications

Metal-organic frameworks (MOFs) are a class of crystalline porous coordination materials, which are assembled from inorganic nodes and organic linkers. Numerous applications, such as gas storage,…

The Adsorption of Small Molecules on the Copper Paddle-Wheel: Influence of the Multi-Reference Ground State

We report a theoretical study of the adsorption of a set of small molecules (C2H2, CO, CO2, O2, H2O, CH3OH, C2H5OH) on the metal centers of the “copper paddle-wheel”—a key structural motif of many…

Beyond Solution Chemistry: Mechanochemistry Enables Clustered Defects in Metal-Organic Frameworks.

Defects in metal-organic frameworks (MOFs) have attracted significant attention in recent years due to the unique properties arising from missing linkers and/or metal nodes. In this work, we…

Benefits and complexity of defects in metal-organic frameworks

Magnetic S-Functionalized Nanoporous Zr-Metal Organic Frameworks with Defect-Induced Performance in Hg(II) Removal

Influencing electrocatalytic processes through topographically disordered atomic sites