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tris(tetrachlorobenzenediolato)phosphate(V)

Known as: TRISPHAT 
National Institutes of Health

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1 relation

Broader (1)

Organophosphorus Compounds

Papers overview

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2010
2010
Resolution of conformationally chiral mer-[Ru(dqp)2]2+ and crystallographic analysis of [delta,delta-Ru(dqp)2][Delta-TRISPHAT]2 (dqp=2,6-di(quinolin-8-yl)pyridine; TRISPHAT=tris…
Resolving the problem! The conformationally chiral bistridentate [Ru(dqp)2]2+ complex (dqp=2,6-di(quinolin-8-yl)pyridine) was… 
2010
2010
Resolution of the first nonracemic diquats.
Three tricyclic diquats with an eight-membered ring were prepared and shown to be the first configurationally stable derivatives… 
2005
2005
Vibrational and electronic circular dichroism of delta-TRISPHAT [tris(tetrachlorobenzenediolato)phosphate(V)] anion.
Herein is reported an experimental and theoretical study of the circular dichroism properties of TRISPHAT (1) anion. ECD analysis… 
2005
2005
Fluorinated TRISPHAT anions: spectroscopic probes for detailed asymmetric ion pairing studies.
Placing fluorine atoms at selected positions allows enantiopure hexacoordinate phosphate anions to behave as effective chiral… 
Highly Cited
2004
Highly Cited
2004
Large-scale synthesis and resolution of TRISPHAT [tris(tetrachlorobenzenediolato) phosphate(V)] anion.
Both enantiomers of TRISPHAT anion can be obtained on a multigram scale through a novel resolution procedure. The Lambda… 
2004
2004
Supramolecular stereocontrol of octahedral metal-centered chirality. Ligand modulation.
By associating chiral labile [FeL3](2+) complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is… 
2004
2004
1H, (19)F, and (31)P PGSE NMR diffusion studies on chiral organic salts: ion pairing and the dependence of a diffusion value on diastereomeric structure.
1H, (19)F and (31)P pulsed field gradient spin-echo (PGSE) diffusion studies on chiral organic salts that contain hexacoordinate… 
2002
2002
Conformational preference and configurational control of highly symmetric spirobi[dibenzazepinium] cation.
[formula: see text] Stereodynamics were detected in solution for salts of the simple spirobi[dibenzazepinium] cation in favor of… 
Highly Cited
2000
Highly Cited
2000
Efficient Enantioselective Extraction of Tris(diimine)ruthenium(II) Complexes by Chiral, Lipophilic TRISPHAT Anions This work was supported by the Swiss National Science Foundation. We thank A. Pinto…
2000
2000
Efficient resolution of a dinuclear triple helicate by asymmetric extraction/precipitation with TRISPHAT anions as resolving agents.
Tetradentate 1,2-bis[4-(4'-methyl-2,2'-bipyridyl)]ethane ligand (3) and Fe(NH4)2(SO4)2.6H2O combine in a 3:2 ratio to form the… 
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