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trichlorosilane

National Institutes of Health

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Silanes

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Highly Cited
2012
Highly Cited
2012
Trichlorosilane mediated asymmetric reductions of the C=N bond.
Chiral amines are key components in numerous bioactive molecules. The development of efficient and economical ways to access… 
Highly Cited
2010
Highly Cited
2010
Diastereo- and enantioselective reductive aldol reaction with trichlorosilane using chiral Lewis bases as organocatalysts.
The catalytic enantioselective tandem reaction is an efficient synthetic methodology in which optically active compounds are… 
Review
2009
Review
2009
Lewis base stabilized dichlorosilylene.
The chemistry of silicon is mainly based on silicon(IV), whereas that of silicon(II) is still in its infancy. Silylene (R2Si:) is… 
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Highly Cited
2009
Highly Cited
2009
Asymmetric reduction of imines with trichlorosilane, catalyzed by sigamide, an amino acid-derived formamide: scope and limitations.
Enantioselective reduction of ketimines 6-10 with trichlorosilane can be catalyzed by the N-methyl valine-derived Lewis-basic… 
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Highly Cited
2008
Highly Cited
2008
Lewis base-catalyzed conjugate reduction and reductive aldol reaction of alpha,beta-unsaturated ketones using trichlorosilane.
Lewis bases such as Ph3P=O and HMPA catalyze the 1,4-reduction of alpha,beta-unsaturated ketones with trichlorosilane, and… 
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Highly Cited
2007
Highly Cited
2007
Organocatalysis with a fluorous tag: asymmetric reduction of imines with trichlorosilane catalyzed by amino acid-derived formamides.
Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by N-methylvaline-derived Lewis-basic formamides 3a-d… 
Highly Cited
2006
Highly Cited
2006
New organic activators for the enantioselective reduction of aromatic imines with trichlorosilane
Abstract N -Picolinoyl-(2 S )-(diphenylhydroxymethyl)pyrrolidine was found to work as an organic activator in the reduction of… 
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Highly Cited
2004
Highly Cited
2004
Role of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilane.
[reaction: see text] Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by a new N-methyl L-valine derived… 
Highly Cited
2003
Highly Cited
2003
Chiral bisphosphine BINAP-stabilized gold and palladium nanoparticles with small size and their palladium nanoparticle-catalyzed asymmetric reaction.
The reduction of tetrachloroaurate or potassium tetrachloropalladate with sodium borohydride in the presence of optically active… 
Highly Cited
1988
Highly Cited
1988
Incorporation of phenoxy groups in self-assembled monolayers of trichlorosilane derivatives. Effects on film thickness, wettability, and molecular orientation.
To evaluate the possibilities for preparing monolayer films from trichlorosilane derivatives containing aromatic functional… 
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