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trichlorosilane

National Institutes of Health

Papers overview

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Highly Cited
2012
Highly Cited
2012
Chiral amines are key components in numerous bioactive molecules. The development of efficient and economical ways to access… 
Highly Cited
2010
Highly Cited
2010
The catalytic enantioselective tandem reaction is an efficient synthetic methodology in which optically active compounds are… 
Review
2009
Review
2009
The chemistry of silicon is mainly based on silicon(IV), whereas that of silicon(II) is still in its infancy. Silylene (R2Si:) is… 
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Highly Cited
2009
Highly Cited
2009
Enantioselective reduction of ketimines 6-10 with trichlorosilane can be catalyzed by the N-methyl valine-derived Lewis-basic… 
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Highly Cited
2008
Highly Cited
2008
Lewis bases such as Ph3P=O and HMPA catalyze the 1,4-reduction of alpha,beta-unsaturated ketones with trichlorosilane, and… 
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Highly Cited
2007
Highly Cited
2007
Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by N-methylvaline-derived Lewis-basic formamides 3a-d… 
Highly Cited
2006
Highly Cited
2006
Abstract N -Picolinoyl-(2 S )-(diphenylhydroxymethyl)pyrrolidine was found to work as an organic activator in the reduction of… 
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Highly Cited
2004
Highly Cited
2004
[reaction: see text] Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by a new N-methyl L-valine derived… 
Highly Cited
2003
Highly Cited
2003
The reduction of tetrachloroaurate or potassium tetrachloropalladate with sodium borohydride in the presence of optically active… 
Highly Cited
1988
Highly Cited
1988
To evaluate the possibilities for preparing monolayer films from trichlorosilane derivatives containing aromatic functional… 
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