roseophilin
National Institutes of Health
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The current literature for the synthesis of pyrazole derivatives has been reviewed. A silver nitrate-induced 5-endo-dig approach…
The pigment Roseophilin is a novel antibiotic with a topologically unique skeleton incorporating an ansa-bridged 1-azafulvene…
[formula: see text] An enantioselective formal total synthesis of roseophilin 3 is presented. The 13-membered ring of…
An enantioselective variant of the synthesis of cross-conjugated cyclopentenones, based on D-glucose-derived chiral auxiliaries…
The homolytic Brook rearrangement is discussed and homolytic fragmentations of epoxides and epoxysilane chemistry are reviewed…