roseophilin
National Institutes of Health
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An 11-step total synthesis of either enantiomer of roseophilin has been developed. The chemistry features effective production of…
Roseophilin,a novel antibiotic isolated from streptomyces griseoviridis,has a unique skeleton combining a 13-membered macrocyclic…
Three different procedures are compared to obtain properly substituted divinyl ketones in which one of the double bonds is…
[reaction: see text] Preparation of a cyclopentenone-fused pyrrolophane, which serves as a model for the tricyclic core of…
Roseophilin (1), a secondary metabolite isolated from a culture broth of Streptomyces griseoviridis, has attracted considerable…
The pigment Roseophilin is a novel antibiotic with a topologically unique skeleton incorporating an ansa-bridged 1-azafulvene…
[formula: see text] An enantioselective formal total synthesis of roseophilin 3 is presented. The 13-membered ring of…
An enantioselective variant of the synthesis of cross-conjugated cyclopentenones, based on D-glucose-derived chiral auxiliaries…
[formula: see text] The formal total synthesis of the macrocyclic core of roseophilin 4 has been accomplished in 12 steps from 5…