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methylenecyclopropane

National Institutes of Health

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Cyclopropanes

Papers overview

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2017
2017
Methylenecyclopropane Ring Formation/Opening Cascade for the Synthesis of Indolizines.
A unique strategy toward the synthesis of polysubstituted indolizines has been developed. When 2-pyridinyl-2-(2'-bromoallyl)-1… 
2008
2008
Lewis acid catalyzed ring-opening intramolecular Friedel-Crafts alkylation of methylenecyclopropane 1,1-diesters.
The first Friedel-Crafts reaction initiated by the direct generation of a carbocation at the C3 position of MCP 1,1-diesters… 
Highly Cited
2007
Highly Cited
2007
Enantioselective catalytic ring expansion of methylenecyclopropane carboxamides promoted by a chiral magnesium Lewis acid.
A catalytic enantioselective ring expansion of monoactivated methylenecyclopropanes (MCP) in the presence of N-tosyl aldimines… 
2006
2006
The singlet-triplet gap in trimethylenmethane and the ring-opening of methylenecyclopropane: a multireference Brillouin-Wigner coupled cluster study.
We performed an ab initio study of the singlet-triplet gap in trimethylenmethane (TMM) and of the ring-opening of… 
2003
2003
Structure-activity relationships of (S,Z)-2-aminopurine methylenecyclopropane analogues of nucleosides. Variation of purine-6 substituents and activity against herpesviruses and hepatitis B virus.
A series of 13 new (S,Z)-2-aminopurine methylenecyclopropane analogues was synthesized, and their antiviral activity was… 
2003
2003
Efficacy of Methylenecyclopropane Analogs of Nucleosides Against Herpesvirus Replication In Vitro
Abstract We have reported previously that purine methylenecyclopropane analogs are potent agents against cytomegaloviruses. In an… 
2003
2003
Spectroscopic and calorimetric studies on the mechanism of methylenecyclopropane rearrangements triggered by photoinduced electron transfer.
2-(dideuteriomethylene)-1,1-bis(4-methoxyphenyl)cyclopropane (d(2)-1) undergoes degenerate rearrangement in both singlet- and… 
Review
2002
Review
2002
Lipophilic phosphoramidates as antiviral pronucleotides.
2000
2000
In Vitro Activities of Methylenecyclopropane Analogues of Nucleosides and Their Phosphoralaninate Prodrugs against Cytomegalovirus and Other Herpesvirus Infections
ABSTRACT Human cytomegalovirus (HCMV) infection does not generally cause problems in the immunocompetent adult but can result in… 
Highly Cited
1996
Highly Cited
1996
TRIMETHYLENEMETHANE. COMPARISON OF MULTICONFIGURATION SELF-CONSISTENT FIELD AND DENSITY FUNCTIONAL METHODS FOR A NON-KEKULE HYDROCARBON
Relative energies for different multiplets of trimethylenemethane and methylenecyclopropane are calculated at MCSCF, CASPT2N, and… 
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