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methyl malonate

Known as: dimethyl malonate 
National Institutes of Health

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Malonates

Papers overview

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2010
2010
Mechanism of enantioselective C-C bond formation with bifunctional chiral ru catalysts: NMR and DFT study.
The mechanism of Michael addition reactions of 1,3-dicarbonyl compounds to cyclic enones catalyzed by bifunctional Ru catalysts… 
Highly Cited
2008
Highly Cited
2008
Organic carbonates as alternative solvents for palladium-catalyzed substitution reactions.
Organic carbonates, such as propylene carbonate, butylene carbonate, and diethyl carbonate, were tested in the Pd-catalyzed… 
2007
2007
Using a tripod as a chiral chelating ligand: chemical exchange between equivalent molecular structures in palladium catalysis with 1,1,1-tris(oxazolinyl)ethane ("trisox").
Threefold symmetrical chiral podands may simplify the stereochemistry of key catalytic intermediates for cases in which they only… 
2006
2006
Stereoselective formation of a single-stranded helicate: structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution.
Chiral C2-symmetric quaterpyridine L reacts with [Pd(eta3-C3H5)Cl]2 to form a chiral single-stranded helical binuclear palladium… 
2004
2004
Preparation of enantiopure biimidazoline ligands and their use in asymmetric catalysis.
A convenient new method for the preparation of 2,2'-biimidazolines is reported. Amino alcohols were reacted with dimethyl oxalate… 
2002
2002
Solvent-dependent dynamic kinetic asymmetric transformation/kinetic resolution in molybdenum-catalyzed asymmetric allylic alkylations.
Catalytic asymmetric alkylation reactions of branched racemic carbonates 1a and 1b with sodium dimethyl malonate, promoted by… 
2000
2000
New hybrid ligands with a trans-1,2-diaminocyclohexane backbone: competing chelation modes in palladium-catalyzed enantioselective allylic alkylation
Three new hybrid ligands with trans-1,2-diaminocyclohexane backbone have been synthesized from (1R,2R)-2-aminocyclohexylcarbamic… 
Highly Cited
1999
Highly Cited
1999
Total Synthesis of the CP Molecules CP-263,114 and CP-225,917- Part 1: Synthesis of Key Intermediates and Intelligence Gathering.
A synthetic labyrinth endowed with countless obstacles, yet filled with numerous hidden treasures, had to be overcome to reach… 
1999
1999
Proline-Based P,N Ligands in Palladium-Catalyzed Asymmetric pi-Allyl Additions.
Excellent yields and at least 95 % ee can be achieved for the addition of dimethyl malonate to cycloalkenyl acetates by using a… 
1998
1998
Enantio- and regiocontrol in palladium- and tungsten-catalyzed allylic substitutions
Abstract 
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