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manganese(V)-oxo corrolazine

 
National Institutes of Health

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Metalloporphyrins

Papers overview

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2016
2016
Visible light-induced formation of corrole-manganese(V)-oxo complexes: Observation of multiple oxidation pathways.
Two manganese(V)-oxo corroles [MnV(Cor)O] that differ in their electronic environments were produced by visible light irradiation… Expand
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Highly Cited
2015
Highly Cited
2015
A Balancing Act: Stability versus Reactivity of Mn(O) Complexes.
A large class of heme and non-heme metalloenzymes utilize O2 or its derivatives (e.g., H2O2) to generate high-valent metal-oxo… Expand
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2014
2014
Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
The reaction of a manganese(V)–oxo porphyrinoid complex with the Lewis acid B(C6F5)3 leads to reversible stabilization of the… Expand
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2011
2011
A manganese(V)-oxo π-cation radical complex: influence of one-electron oxidation on oxygen-atom transfer.
One-electron oxidation of Mn(V)-oxo corrolazine 2 affords 2(+), the first example of a Mn(V)(O) π-cation radical porphyrinoid… Expand
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2010
2010
Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(V)-oxo corrolazine complex.
The reactivity of high-valent metal–oxo species is critical to the functioning of a large class of metalloenzymes. In heme… Expand
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2010
2010
Manganese(V)-oxo corroles in hydride-transfer reactions.
Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(V)-oxo corroles proceeds via proton… Expand
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2006
2006
Hydrogen atom abstraction by a high-valent manganese(V)-oxo corrolazine.
High-valent metal-oxo complexes are postulated as key intermediates for a wide range of enzymatic and synthetic processes. To… Expand
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2006
2006
Characterization of manganese(V)-oxo polyoxometalate intermediates and their properties in oxygen-transfer reactions.
A manganese(III)-substituted polyoxometalate, [alpha2-P2MnIII(L)W17O61]7- (P2W17MnIII), was studied as an oxidation catalyst… Expand
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2005
2005
Synthesis, characterization, and physicochemical properties of manganese(III) and manganese(V)-oxo corrolazines.
The structural and physicochemical properties of the manganese-corrolazine (Cz) complexes (TBP8Cz)Mn(V)O (1) and (TBP8Cz)Mn(III… Expand
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2002
2002
A stable manganese(V)-oxo corrolazine complex.
The synthesis and characterization of an oxomanganese(V) corrolazine, (TBP)8(Cz)Mn(V)O (2), are reported. This remarkably stable… Expand
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