manganese(V)-oxo corrolazine
National Institutes of Health
Papers overview
Semantic Scholar uses AI to extract papers important to this topic.
A large class of heme and non-heme metalloenzymes utilize O2 or its derivatives (e.g., H2O2) to generate high-valent metal-oxo…
The reaction of a manganese(V)–oxo porphyrinoid complex with the Lewis acid B(C6F5)3 leads to reversible stabilization of the…
One-electron oxidation of Mn(V)-oxo corrolazine 2 affords 2(+), the first example of a Mn(V)(O) π-cation radical porphyrinoid…
The reactivity of high-valent metal–oxo species is critical to the functioning of a large class of metalloenzymes. In heme…
Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(V)-oxo corroles proceeds via proton…
High-valent metal-oxo complexes are postulated as key intermediates for a wide range of enzymatic and synthetic processes. To…
A manganese(III)-substituted polyoxometalate, [alpha2-P2MnIII(L)W17O61]7- (P2W17MnIII), was studied as an oxidation catalyst…
The structural and physicochemical properties of the manganese-corrolazine (Cz) complexes (TBP8Cz)Mn(V)O (1) and (TBP8Cz)Mn(III…
The synthesis and characterization of an oxomanganese(V) corrolazine, (TBP)8(Cz)Mn(V)O (2), are reported. This remarkably stable…