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manganese(V)-oxo corrolazine
Papers overview
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Highly Cited
2015
Highly Cited
2015
A large class of heme and non-heme metalloenzymes utilize O2 or its derivatives (e.g., H2O2) to generate high-valent metal-oxo… Expand
2014
2014
The reaction of a manganese(V)–oxo porphyrinoid complex with the Lewis acid B(C6F5)3 leads to reversible stabilization of the… Expand
Highly Cited
2011
Highly Cited
2011
One-electron oxidation of Mn(V)-oxo corrolazine 2 affords 2(+), the first example of a Mn(V)(O) π-cation radical porphyrinoid… Expand
Highly Cited
2010
Highly Cited
2010
Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(V)-oxo corrolazine complex.
The reactivity of high-valent metal–oxo species is critical to the functioning of a large class of metalloenzymes. In heme… Expand
2010
2010
Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(V)-oxo corroles proceeds via proton… Expand
Highly Cited
2006
Highly Cited
2006
High-valent metal-oxo complexes are postulated as key intermediates for a wide range of enzymatic and synthetic processes. To… Expand
Highly Cited
2006
Highly Cited
2006
A manganese(III)-substituted polyoxometalate, [alpha2-P2MnIII(L)W17O61]7- (P2W17MnIII), was studied as an oxidation catalyst… Expand
2006
Highly Cited
2005
Highly Cited
2005
The structural and physicochemical properties of the manganese-corrolazine (Cz) complexes (TBP8Cz)Mn(V)O (1) and (TBP8Cz)Mn(III… Expand
Highly Cited
2002
Highly Cited
2002
The synthesis and characterization of an oxomanganese(V) corrolazine, (TBP)8(Cz)Mn(V)O (2), are reported. This remarkably stable… Expand