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lithium 2,2,6,6-tetramethylpiperidide

National Institutes of Health

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Organometallic Compounds

Papers overview

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2018
2018
Deprotonative Metalation of Methoxy-Substituted Arenes Using Lithium 2,2,6,6-Tetramethylpiperidide: Experimental and Computational Study.
The reaction pathways of lithium 2,2,6,6-tetramethylpiperidide (LiTMP)-mediated deprotonative metalation of methoxy-substituted… 
2012
2012
syn-β-Hydroxyallylic silanes from terminal epoxide α-lithiation-silylation and alkenylation: application to the tetrahydrofuran portion of the lytophilippines.
Lithiation-in situ silylation of terminal epoxides using lithium 2,2,6,6-tetramethylpiperidide in combination with phenyldimethyl… 
2010
2010
Stereocontrolled syntheses of (-)-cubebol and (-)-10-epicubebol involving intramolecular cyclopropanation of alpha-lithiated epoxides.
Formylation of (-)-menthone (11) with LDA and HCO(2)CH(2)CF(3) avoids loss of configurational integrity at the isopropyl group… 
2008
2008
Prototropic rearrangements in cycloheptatrienyl PCP pincer iridium complexes.
When the cycloheptatriene iridium(iii) pincer complex (PCP)Ir(CO)(H)(Cl) (3) (PCP = 2,7-(CH(2)P(t)Bu(2))(2)C(7)H(5)) is treated… 
2007
2007
The reactivity of epoxides with lithium 2,2,6,6-tetramethylpiperidide in combination with organolithiums or grignard reagents.
The scope and limitations of lithium 2,2,6,6-tetramethylpiperidide (LTMP)-modified reductive alkylation of epoxides is detailed… 
2003
2003
Lithium 2,2,6,6-Tetramethylpiperidide-Mediated α- and β-Lithiations of Epoxides: Solvent-Dependent Mechanisms
Lithium 2,2,6,6-tetramethylpiperidide (LiTMP)-mediated α- and β-lithiations of epoxides are described. LiTMP displays a markedly… 
2001
2001
Directed deprotonation-transmetalation as a route to substituted pyridines.
Regioselective C-4 deprotonation of 3-bromopyridine, followed by Li/Zn transmetalation and Pd-mediated coupling processes… 
2000
2000
Enhancement of Benzylic basicity by a fluorine substituent at the para- position: a case of lone pair/lone pair repulsion
The introduction of a halogen atom at any aromatic position of toluene considerably accelerates the base-promoted deprotonation… 
1999
1999
Mixed Crossed Aldol Condensation between Conjugated Esters and Aldehydes Using Aluminum Tris(2,6-diphenylphenoxide).
The combined use of aluminum tris(2,6-diphenylphenoxide) (ATPH) and lithium 2,2,6,6-tetramethylpiperidide (LTMP) has proven to be… 
Highly Cited
1991
Highly Cited
1991
A new class of HIV-1-specific 6-substituted acyclouridine derivatives: synthesis and anti-HIV-1 activity of 5- or 6-substituted analogues of 1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)thymine (HEPT).
A series of novel acyclouridine derivatives substituted at both the C-5 and C-6 positions were synthesized for the purpose of… 
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