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linamarin synthase activity

Known as: UDP glucose ketone cyanohydrin glucosyltransferase activity, uridine diphosphate-glucose-ketone cyanohydrin beta-glucosyltransferase activity, UDP-glucose:2-hydroxy-2-methylpropanenitrile beta-D-glucosyltransferase activity 
Catalysis of the reaction: UDP-glucose + 2-hydroxy-2-methylpropanenitrile = UDP + linamarin. [EC:2.4.1.63, MetaCyc:LINAMARIN-SYNTHASE-RXN]
National Institutes of Health

Papers overview

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2013
2013
Efficient synthesis of cyanohydrin trimethylsilyl ethers via 1,2-chemoselective cyanosilylation of carbonyls
Here we report a sustainable protocol for the cyanosilylation of carbonyl compounds 1a–g and 3a–m using trimethylsilyl cyanide… 
2010
2010
Organocatalytic synthesis of cyanohydrin trimethylsilyl ethers by potassium 4‐benzylpiperidinedithiocarbamate under solvent‐free conditions
Potassium 4-benzylpiperidinedithiocarbamate was found to be an efficient organocatalyst for facile addition of trimethylsilyl… 
2009
2009
Investigation of the reactivity of Pt phosphinito and molybdocene nitrile hydration catalysts with cyanohydrins.
Aldehyde- and ketone-derived cyanohydrins were reacted with the nitrile hydration catalysts [PtCl(PR(2)OH){(PR(2)O)(2)H}] (1) and… 
2009
2009
Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones
A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields… 
2003
2003
New aspects in pathogenesis of konzo: neural cell damage directly caused by linamarin contained in cassava (Manihot esculenta Crantz)
Epidemic spastic paraparesis (konzo) found in tropical and subtropical countries is known to be caused by long-term intake of… 
1996
1996
Biosynthesis of cyanohydrin glucosides from unnatural nitriles in intact tissue of Passiflora morifolia and Turnera angustifolia.
1994
1994
Purification, characterization, and cloning of alpha-hydroxynitrile lyase from cassava (Manihot esculenta Crantz).
alpha-Hydroxynitrile lyase (HNL, acetone cyanohydrin lyase, EC 4.1.2.37) was purified to homogeneity from young leaves of the… 
Highly Cited
1993
Highly Cited
1993
Improved purification of an (R)‐oxynitrilase from Linum usitatissimum (flax) and investigation of the substrate range
The purification of (R)‐oxynitrilase (EC 4.1.2.10) from Linum usitatissimum (flax) has been improved considerably. The enzyme is… 
1988
1988
Novel Cyclopentenoid Cyanohydrin Rhamnoglucosides from Flacourtiaceae1
S R R S O L D Hydnocarpus pentandra L D 
1985
1985
Effect of thiamin status on the metabolism of linamarin in rats.
The effect of graded levels of thiamin on the metabolism of linamarin was investigated in rats. It was observed that on a diet… 
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