iron hydrogenase

A new biomimetic heterogeneous photocatalyst ([FeFe]@ZrPF) has been synthesized through the incorporation of homogeneous complex… (More)

The protonation behavior of the iron hydrogenase active-site mimic [Fe2(mu-adt)(CO)4(PMe3)2] (1; adt=N-benzyl-azadithiolate) has… (More)

The first model of the iron hydrogenase active site has been prepared which concomitantly carries a proton and a hydride; the… (More)

The first ruthenium-diiron complex [(mu-pdt)Fe2(CO)5{PPh2(C6H4CCbpy)}Ru(bpy)2]2+ 1 (pdt = propyldithiolate, bpy = 2,2'-bipyridine… (More)

The first model of the iron hydrogenase active site has been prepared in which an amine ligand is loosely coordinated to an Fe(i… (More)

A model of the iron hydrogenase active site with the structure [(mu-ADT)Fe2(CO)6] (ADT = azadithiolate (S-CH2-NR-CH2-S), (2: R… (More)

Reaction of Fe(2)(mu-S(2)C(3)H(6))(CO)(6) (1) with 2 equiv of t-BuNC affords a disubstitued species Fe(2)(mu-S(2)C(3)H(6))(CN-t… (More)

Hydrogen uptake in hydrogenase enzymes can be assayed by H/D exchange reactivity in H(2)/D(2)O or H(2)/D(2)/H(2)O mixtures… (More)

Iron(I) in biology?: one-electron oxidation of an (Fe(I)-Fe(I)) carbonyl cyanide precursor bearing a proximal thioether group… (More)

Hydrogen evolution is observed in the green alga Scenedesmus obliquus after a phase of anaerobic adaptation. In this study we… (More)