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dirhodium tetracarboxylate

National Institutes of Health

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Organometallic Compounds

Papers overview

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2011
2011
Pentasubstituted ferrocene and dirhodium(II) tetracarboxylate as building blocks for discrete fullerene-like and extended supramolecular structures.
The synthesis of a penta(1-methylpyrazole)ferrocenyl phosphine oxide ligand (1) [Fe(C(5)(C(3)H(2)N(2)CH(3))(5))(C(5)H(4)PO(t-C(4… 
2010
2010
Experimental verification of diverging mechanisms in the binding of ether, thioether, and sulfone ligands to a dirhodium tetracarboxylate
Complexation of the oxygen atom in 2‐butylphenylethers and sulfur in 2‐butylphenylthioethers to a rhodium atom in dirhodium… 
2009
2009
Comparing various chiral dirhodium tetracarboxylates in the dirhodium method.
Three enantiopure dirhodium tetracarboxylates are compared in their NMR properties to differentiate chiral ligands of various… 
2008
2008
Origin of 13C complexation shifts in the adduct formation of 2‐butyl phenyl ethers with a dirhodium tetracarboxylate complex
Complexation of the oxygen atom in 2‐butyl phenyl ethers to a rhodium atom of the dirhodium tetracarboxylate Rh(II)2[(R)‐(+)‐MTPA… 
2008
2008
Mechanism and control of rare tautomer trapping at a metal-metal bond: adenine binding to dirhodium antitumor agents.
The cause of mutations in the genome by the occurrence of nuclebases in their rare tautomeric forms was first proposed by Watson… 
Highly Cited
2007
Highly Cited
2007
A DFT study on the mechanism of Rh2(II,II)-catalyzed intramolecular amidation of carbamates.
The potential-energy surfaces of the reactions of dirhodium tetracarboxylate (Rh2(II,II)) catalyzed nitrene (NR) insertion into C… 
2006
2006
Entrapment of a dirhodium tetracarboxylate unit inside the aromatic bowl of a calix[4]arene: unique catalysts for C-H amination.
Unique calix[4]arene-derived, tetracarboxylate dirhodium(II) inclusion complexes have been prepared and evaluated as catalysts… 
2002
2002
Functional mimic of dioxygen-activating centers in non-heme diiron enzymes: mechanistic implications of paramagnetic intermediates in the reactions between diiron(II) complexes and dioxygen.
Two tetracarboxylate diiron(II) complexes, [Fe(2)(mu-O(2)CAr(Tol))(2)(O(2)CAr(Tol))(2)(C(5)H(5)N)(2)] (1a) and [Fe(2)(mu-O(2)CAr… 
2001
2001
Using structures formed by dirhodium tetra(trifluoroacetate) with polycyclic aromatic hydrocarbons to prospect for maximum pi-electron density: Hückel calculations get it right.
A new class of supramolecular assemblies derived from a powerful Lewis acid in the form of dirhodium(II) tetra(trifluoroacetate… 
1996
1996
Molecular Structures and Photophysical Properties of Dirhodium Fluorophosphine Complexes.
The excited state properties of a series of singly bonded dirhodium compounds, consisting of Rh(0)(2), Rh(0)Rh(II)X(2), and Rh(II… 
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