dimethoxycarbene

The (4+1)-annulation of dimethoxycarbene with readily accessible α,β-unsaturated carbonyls gives cyclic orthoesters, which can… Expand

The reactions of dimethoxycarbene (DMC; 2), which was generated in situ by thermal decomposition of 2,5-dihydro-2,2-dimethoxy-5,5… Expand

The nucleophilic dimethoxycarbene (DMC; 2) generated by thermal decomposition of 2,5-dihydro-1,3,4-oxadiazole derivative 1 in… Expand

Polycyclic 'cage' ketones, such as pentacyclo[5.4.0.02,6.03,10.05,9]undecan-8-one (10), pentacyclo[5.4.0.02,6.03,10.05,9]undecane… Expand

Dimethoxycarbene, in 2-fold or larger excess, reacts with dimethyl 2,3-dicyanomaleate and fumarate to afford an unstable… Expand

The zwitterion formed by the reaction of dimethoxycarbene and DMAD adds efficiently to one of the carbonyl groups of 1,2… Expand

[reaction: see text] Highly substituted beta-lactams have been isolated as the major product of the reaction of dimethoxycarbene… Expand

[reaction: see text] At 50 degrees C, dimethyl dicyanofumarate and maleate react with 2 equiv of dimethoxycarbene to generate the… Expand

Reaction of dimethoxycarbene (DMC), generated by thermolysis of a 2,5-dihydro-1,3,4-oxadiazole, with 2,2,4,4-tetramethyl-3… Expand

Gas phase thermolysis of 2,2-dimethoxy-5,5-dimethyl-Δ 3 -1,3,4-oxadiazoline (1) in an ultraviolet photoelectron spectrometer by… Expand