dimethoxycarbene
National Institutes of Health
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The (4+1)-annulation of dimethoxycarbene with readily accessible α,β-unsaturated carbonyls gives cyclic orthoesters, which can…
The reactions of dimethoxycarbene (DMC; 2), which was generated in situ by thermal decomposition of 2,5-dihydro-2,2-dimethoxy-5,5…
Dimethoxycarbene, in 2-fold or larger excess, reacts with dimethyl 2,3-dicyanomaleate and fumarate to afford an unstable…
The zwitterion formed by the reaction of dimethoxycarbene and DMAD adds efficiently to one of the carbonyl groups of 1,2…
[reaction: see text] At 50 degrees C, dimethyl dicyanofumarate and maleate react with 2 equiv of dimethoxycarbene to generate the…
Reaction of dimethoxycarbene (DMC), generated by thermolysis of a 2,5-dihydro-1,3,4-oxadiazole, with 2,2,4,4-tetramethyl-3…
The potential-energy surfaces for the abstraction reactions of carbenes with oxirane and thiirane have been characterized in…
Compounds of structure 2 are generated by a eheletropie dimethoxycarbene elimination while 3e was isolated in the attempted…