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dimethoxycarbene

 
National Institutes of Health

Topic mentions per year

Topic mentions per year

2000-2017
012320002017

Related topics

Related topics

1 relation
carbene

Related mentions per year

Related mentions per year

1936-2018
19401960198020002020
dimethoxycarbene
carbene

Papers overview

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2017
2017
Reactions of dimethoxycarbene with N-tosylated imines
The reactions of dimethoxycarbene (DMC; 2), which was generated in situ by thermal decomposition of 2,5-dihydro-2,2-dimethoxy-5,5… (More)
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2017
2017
The First Reaction of Dimethoxycarbene with an Imine
The nucleophilic dimethoxycarbene (DMC; 2) generated by thermal decomposition of 2,5dihydro-1,3,4-oxadiazole derivative 1 in… (More)
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2017
2017
Reactions of Polycyclic Ketones with Dimethoxycarbene; a Convenient Route for a ’One-pot’ Preparation of Some α-Hydroxycarboxylic Esters
Polycyclic ’cage’ ketones, such as pentacyclo[5.4.0.02,6.03,10.05,9]undecan-8-one (10), pentacyclo[5.4.0.02,6.03,10.05,9… (More)
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2007
2007
Reactions of dimethoxycarbene with dimethyl 2,3-dicycanomaleate and fumarate.
Dimethoxycarbene, in 2-fold or larger excess, reacts with dimethyl 2,3-dicyanomaleate and fumarate to afford an unstable… (More)
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2006
2006
Reaction of dimethoxycarbene-DMAD zwitterion with 1,2-diones and anhydrides: a novel synthesis of highly substituted dihydrofurans and spirodihydrofurans.
The zwitterion formed by the reaction of dimethoxycarbene and DMAD adds efficiently to one of the carbonyl groups of 1,2… (More)
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2006
2006
New entry into beta-lactams via reaction of dimethoxycarbene with isocyanates.
[reaction: see text] Highly substituted beta-lactams have been isolated as the major product of the reaction of dimethoxycarbene… (More)
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2005
2005
New thermal source of dimethoxycarbene leading to zwitterionic intermediates and 2:1 stoichiometry in reaction with electrophilic alkenes.
[reaction: see text] At 50 degrees C, dimethyl dicyanofumarate and maleate react with 2 equiv of dimethoxycarbene to generate the… (More)
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2003
2003
Strategies for heterocyclic construction via novel multicomponent reactions based on isocyanides and nucleophilic carbenes.
This Account focuses mainly on our recent endeavors in the area of multicomponent reactions (MCRs) involving zwitterionic species… (More)
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2002
2002
Relative reactivities of carbonyl and thiocarbonyl groups toward dimethoxycarbene: two new dimethoxythiiranes.
Reaction of dimethoxycarbene (DMC), generated by thermolysis of a 2,5-dihydro-1,3,4-oxadiazole, with 2,2,4,4-tetramethyl-3… (More)
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2000
2000
Deoxygenation and desulfurization of oxiranes and thiiranes by carbenes: a theoretical study
The potential-energy surfaces for the abstraction reactions of carbenes with oxirane and thiirane have been characterized in… (More)
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