aziridinomitosene
National Institutes of Health
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The syntheses and reactivity of N-TBDPS and N-trityl protected derivatives of an aziridinomitosene corresponding to FK317 are…
Anionic aromatic ipso-substitution has allowed an aziridine ring to be fused onto pyrrolo[1,2-a]benzimidazole. This diazole…
The clinically used antitumor antibiotic mitomycin C requires a reductive activation to be converted to a bis-electrophile that…
Highly substituted, tethered alkyne dipolarophiles participate in the internal 2 + 3 cycloaddition with azomethine ylides…
Hindered N-silylamines were examined for their utility to serve as protecting groups for the labile aziridine nitrogen found…
The bicyclic pyrrole ketone 16 has been prepared by using an oxaza-Claisen rearrangement, followed by nitrogen deprotection…
A convergent synthetic route to the 1,2-aziridinopyrrolo(1,2-a)indole 34 has been developed. Key features of this route include…
Treatment of 11a with methyllithium affords the destannylated product 12 together with a small amount of tetracyclic product…