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allyltrimethylsilane

National Institutes of Health

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Trimethylsilyl Compounds

Papers overview

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2014
2014
Titanium Tetrafluoride/L-Prolinol Catalyzed Enantioselective Allylation of Aromatic Aldehydes with Allyltrimethylsilane
Aldehydes undergo smooth conversion to give homoallylic alcohols with allyltrimethylsilane employing 10 mol% of titanium… 
2012
2012
Mild and Efficient Tris(pentafluorophenyl)borane-catalyzed Sakurai Allylation of N-Benzyloxycarbonylamino p-Tolylsulfone with Allyltrimethylsilane
, was found to be an efficient catalyst for synthesis of N-Cbz-homoallylic amines using Sakurai allylation of N-benzyloxycarbonyl… 
2009
2009
Highly regioselective gold-catalyzed ring-opening allylation and azidation of dihydrofurans.
The ring-opening allylation and azidation of 2,5-dihydrofurans has been accomplished with allyltrimethylsilane or Me(3)SiN(3) in… 
2008
2008
Efficient Iron-Catalyzed Sakurai–Michael Addition of Allyltrimethylsilane to Chalcones
A general catalytic conjugate addition with allyltrimethylsilane and chalcones is described. Allyltrimethylsilane undergoes the… 
2006
2006
Addition of Allyltrimethylsilane to tert-Butanesulfinyl Imines Triggered by Tetra-n-butylammonium Fluoride
2004
2004
InBr3-catalyzed deoxygenative allylation of benzylic and allylic alcohols and acetates with allyltrimethylsilane
2002
2002
Synthesis of C‐Glycosides from S‐Glycosyl Phosphorothioates.
Treatment of O-benzyl protected S-glucosyl phosphorothioates with 1,3,5-trimethoxybenzene in the presence of iodine or boron… 
2001
2001
Untersuchungen zur flexiblen Synthese von potentiell flüssigkristallinen Verbindungen auf der Basis von 2,5-di-[C]-substituierten Pyransystemen - Synthese und Anwendung von neuen 2-substituierten…
Durch die fortschreitende Entwicklung in der Mikroelektronik sind Flussig-Kristall-Anzeigen (LCDs) erschwinglich geworden. Aber… 
1999
1999
Allylation of Imines with Allyltrimethylsilane and Experimental Evidences for a Fluoride-Triggered Autocatalysis Mechanism of the Sakurai-Hosomi Reaction
The allylation of carbonyl compound is one of the most important C-C bond forming reactions.1 In addition to the widely used… 
1993
1993
Asymmetric reactions of 8-phenylmenthyl pyruvate with allyltrimethylsilane, silyl enol ethers and ketene silyl acetals
By mediation of TiCl4, allylsilane, silyl enol ethers and ketene silyl acetals attacked (–)phenylmenthyl pyruvate and…