Phospha 250 Neutral Pill

The synthesis of the first phophanylphosphonate, Mes*PH-PO(OEt)2 (2-H), in which the P(III) centre is not coordinated by a M(CO)5… (More)

More than just a carbon copy: The reaction of a phospha-Wittig-Horner reagent with diacetylenic ketones (see scheme) results in a… (More)

The carbene-like chemistry of electrophilic terminal phosphinidene complexes [RP-M(CO)5] (M= Cr, Mo, W) has been heavily… (More)

Phosphaalkenes (MesP=CRR': R = R' = Ph (1a); R = R' = 4-FC6H4 (1b); R = Ph, R' = 4-FC6H4 (1c); R = R' = 4-OMeC6H4 (1d); R = Ph, R… (More)