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Azirines

Known as: Azacyclopropanes, Unsaturated, Azirines [Chemical/Ingredient], Unsaturated Azacyclopropanes 
Unsaturated azacyclopropane compounds that are three-membered heterocycles of a nitrogen and two carbon atoms.
National Institutes of Health

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(3-trifluoromethyl) phenyldiazirine2-azi-2-deoxy-arabino-hexitol3-hydroxyphenyl-3H-diazirine3-trifluoromethyl-3-phenyldiazirine
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Papers overview

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Highly Cited
2015
Highly Cited
2015
Gold-catalyzed intermolecular nitrene transfer from 2H-azirines to ynamides: a direct approach to polysubstituted pyrroles.
An effective gold-catalyzed intermolecular nitrene transfer by the reaction of 2H-azirines and ynamides is reported, which… 
Highly Cited
2015
Highly Cited
2015
Diversity in Gold-Catalyzed Formal Cycloadditions of Ynamides with Azidoalkenes or 2H-Azirines: [3+2] versus [4+3] Cycloadditions.
Gold-catalyzed cycloadditions of ynamides with azidoalkenes or 2H-azirines give [3+2] or [4+3] formal cycloadducts of three… 
Highly Cited
2015
Highly Cited
2015
Rh(II)-catalyzed [3+2] cycloaddition of 2 H-azirines with N-sulfonyl-1,2,3-triazoles.
Rh(II)-catalyzed intermolecular [3+2] cycloaddition of 2 H-azirines with N-sulfonyl-1,2,3-triazoles is disclosed, in which a… 
Highly Cited
2015
Highly Cited
2015
[3 + 2] Cycloaddition/Oxidative Aromatization Sequence via Photoredox Catalysis: One-Pot Synthesis of Oxazoles from 2H-Azirines and Aldehydes.
A novel [3 + 2] cycloaddition/oxidative aromatization sequence via visible light-induced photoredox catalysis is disclosed. It… 
Highly Cited
2015
Highly Cited
2015
Rh(II)-catalyzed cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines: switchable reactivity of Rh-azavinylcarbene as [2C]- or aza-[3C]-synthon.
The Rh(II)-catalyzed formal [3+2] and [3+3] cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines have been developed, which… 
Highly Cited
2014
Highly Cited
2014
Visible-light-induced formal [3+2] cycloaddition for pyrrole synthesis under metal-free conditions.
A photocatalytic formal [3+2] cycloaddition of 2H-azirines with alkynes has been achieved under irradiation by visible light in… 
Highly Cited
2011
Highly Cited
2011
Organocatalytic asymmetric Neber reaction for the synthesis of 2H-azirine carboxylic esters.
The first enantioselective Neber reaction of β-ketoxime sulfonates catalyzed by a bifunctional thiourea has been developed. The… 
2011
2011
Divergent reactivity of α-oximino carbenoids: facile access to 2-isoxazolines and 2H-azirines.
Mild catalytic reaction conditions for the synthesis of 2-isoxazolines and 2H-azirines have been developed via carbenoids derived… 
Review
2009
Review
2009
Addition and Cycloaddition Reactions of Phosphinyl- and Phosphonyl-2H-Azirines, Nitrosoalkenes and Azoalkenes
An overview of the use of 2H-azirines, conjugated nitrosoalkenes and conjugated azoalkenes bearing phosphorus substituents in… 
Highly Cited
2005
Highly Cited
2005
Photochemistry of 2-(1-naphthyl)-2H-azirines in matrixes and in solutions: wavelength-dependent C-C and C-N bond cleavage of the azirine ring.
The photochemistry of 3-methyl-2-(1-naphthyl)-2H-azirine (1a) was investigated by the direct observation of reactive… 
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