Skip to search formSkip to main contentSkip to account menu

Azirines

Known as: Azacyclopropanes, Unsaturated, Azirines [Chemical/Ingredient], Unsaturated Azacyclopropanes 
Unsaturated azacyclopropane compounds that are three-membered heterocycles of a nitrogen and two carbon atoms.
National Institutes of Health

Related topics

Related topics

21 relations

Narrower (15)

(3-trifluoromethyl) phenyldiazirine2-azi-2-deoxy-arabino-hexitol3-hydroxyphenyl-3H-diazirine3-trifluoromethyl-3-phenyldiazirine
In Bloodagonistsantagonists & inhibitorsaspects of radiation effects

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2019
2019
1,3-Dipolar Cycloaddition of Isatin-Derived Azomethine Ylides with 2 H-Azirines: Stereoselective Synthesis of 1,3-Diazaspiro[bicyclo[3.1.0]hexane]oxindoles.
A regio- and diastereoselective 1,3-dipolar cycloaddition of 2 H-azirines with azomethine ylides generated in situ from isatins… 
Review
2019
Review
2019
Enantioselective Reaction of 2H-Azirines.
2H-Azirines are useful precursors for the synthesis of a variety of chiral aziridine and amine derivatives with a range of… 
2018
2018
Copper-Catalyzed Ring-Expansion Cascade of Azirines with Alkynes: Synthesis of Multisubstituted Pyridines at Room Temperature.
The first intermolecular ring-expansion cascade of azirines with alkynes for the synthesis of pyridines, enabled by a copper… 
2017
2017
Ruthenium-Catalyzed Synthesis of 2H-Azirines from Isoxazolinones.
2H-Azirines are synthetically versatile, highly strained, three-membered heterocycles containing an imino double bond. We report… 
2016
2016
Kinetic Resolution of 2H-Azirines by Asymmetric Imine Amidation.
Highly efficient kinetic resolution of 2H-azirines by an asymmetric imine amidation was achieved in the presence of a chiral N,N… 
2013
2013
Cu(II)-catalyzed domino reaction of 2H-azirines with diazotetramic and diazotetronic acids. Synthesis of 2-substituted 2H-1,2,3-triazoles.
The Cu(II)-catalyzed addition of two molecules of a 3-aryl-2H-azirine to diazotetramic or diazotetronic acids proceeds as a… 
Highly Cited
2005
Highly Cited
2005
Photochemistry of 2-(1-naphthyl)-2H-azirines in matrixes and in solutions: wavelength-dependent C-C and C-N bond cleavage of the azirine ring.
The photochemistry of 3-methyl-2-(1-naphthyl)-2H-azirine (1a) was investigated by the direct observation of reactive… 
2003
2003
Stereoselective aza-Diels-Alder reactions with 2H-azirines as dienophiles furnishing highly functionalized tetrahydropyridines.
Highly diastereoselective Lewis acid mediated aza-Diels-Alder reactions of chiral auxiliary derivatized 2H-azirines have been… 
2002
2002
Asymmetric reduction of azirines; a new route to chiral aziridines.
The first enantioselective reduction of aromatic 2H-azirines yields aziridines in up to 70% ee, using the aminoalcohol-[RuCl2(p… 
1996
1996
Photochemistry of Fluorinated Phenyl Nitrenes: Matrix Isolation of Fluorinated Azirines.
2,6-Difluorophenylnitrene and pentafluorophenylnitrene were generated in solid argon at 10 K by irradiation of the corresponding… 
By clicking accept or continuing to use the site, you agree to the terms outlined in our Privacy Policy (opens in a new tab), Terms of Service (opens in a new tab), and Dataset License (opens in a new tab)