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8-thiotheophyllinate-triphenylphosphine gold(I)

Known as: tTAuP 
National Institutes of Health

Related topics

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4 relations

Broader (3)

Organogold CompoundsOrganophosphorus CompoundsTheophylline
analogs & derivatives

Papers overview

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2020
2020
A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior.
New trinuclear gold(i) N-arylimidazolate cluster complexes have been synthesized from cationic [Au(CNR)2]+ isocyanide complexes… 
2020
2020
Metallophilic Au(i)M(i) interactions (M = Tl, Ag) in heteronuclear complexes with 1,4,7-triazacyclononane: structural features and optical properties.
1,4,7-Triazacyclononane (TACN) has been used for the first time to support Au(i)M [M = Tl(i), Ag(i)] metallophilic interactions… 
2018
2018
Heavier pnictinidene gold(i) complexes.
N,C,N-Chelated pnictinidenes ArE [where E = As, Sb or Bi; Ar = 2,6-(tBuN[double bond, length as m-dash]CH)2C6H3] were used as… 
2016
2016
First spectroscopic observation of gold(i) butadiynylide: Photodetachment velocity map imaging of the AuC4H anion.
The velocity map imaging technique was used in the investigation of gold(i) butadiynylide, AuC4H(-), with images recorded at two… 
2014
2014
Different emissive properties in dithiolate gold(i) complexes as a function of the presence of phenylene spacers.
A family of dinuclear neutral thiolate gold complexes of the type RPh2PAuS(C6H4)nSAuPPh2R (n = 2, 3), RPh2PAuS(C6H4)S(C6H4… 
2014
2014
A SYNERGISTIC SYNTHETIC, SPECTROSCOPIC AND COMPUTATIONAL APPROACH TO THE DESIGN OF ORGANOMETALLIC PLATFORMS FEATURING LINEARLY FUNCTIONALIZED AZULENIC AND BIAZULENIC MOTIFS
......................................................................................................................................... iii Acknowledgments.......................................................................................................................... iv List of Tables ................................................................................................................................. xi List of Figures .............................................................................................................................. xiii List of Schemes ............................................................................................................................ xix Abreviations Used ........................................................................................................................ xxi Chapter 1 ....................................................................................................................................... 1 Abstract ........................................................................................................................................... 2.......................................................................................................................................... 2 Introduction ..................................................................................................................................... 2 Experimental ................................................................................................................................... 5 General procedures, starting materials and equipment. .............................................................. 5 Synthesis of 2-thiolate-1,3-diethoxycarbonylazulene gold(I) triphenylphosphine (I.2a) ........... 6 Synthesis of 2-thiolate-azulene gold(I) triphenylphosphine (I.2b) ............................................. 8 Synthesis of 6-thiolate-1, 3-diethoxycarbonylazulene gold(I) triphenylphosphine (I.2c) .......... 8 Synthesis of 6-thiolate-1, 3-diethoxycarbonyl-2’,6-biazulene gold(I) triphenylphosphine (I.2f)9 Density Functional Theory Calculations ................................................................................... 11 Photoluminescence Results ....................................................................................................... 13 X-Ray Diffraction Study of 2-thiolate-1,3-diethoxycarbonylazulene gold(I) triphenylphosphine (I.2a) .......................................................................................................................................... 20 
2011
2011
Enantioselective intermolecular carbon-carbon bond formation of glyoxylate imines with allylstannanes catalyzed by tropos BIPHEP-gold(I) complexes with Au-Au interactions.
Over the last decade, a number of gold-catalyzed intraand intermolecular reactions have been developed on the basis of the unique… 
1997
1997
Ab Initio Molecular Orbital Calculation on Dinuclear Gold(I) Complexes ——Metal Metal Interaction and Electronic Structure of Binuclear Gold(I) Complexes with Bridging Bidentate Ligands *
The electronic structure and electronic absorption spectra of binuclear Au(Ⅰ) complexes with bidentate phophines and a bidentate… 
1993
1993
The (8-thiotheophyllinate) (triphenylphosphine) gold (I), (tTAuP): a new gold complex as an anticancer agent.
1991
1991
Intracellular accumulation and cytotoxic effect of (8-thiotheophyllinate) (triphenylphosphine) gold(I) in Friend leukemia cells.
Following continuous exposure to tTAuP in medium containing 10% fetal calf serum (FCS), cells resistant to doxorubicin (DOX-RFLC… 
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