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2,2,2-trifluorodiazoethane

National Institutes of Health

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2 relations

Broader (2)

Azo CompoundsHydrocarbons, Fluorinated

Papers overview

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2018
2018
Zinc-Mediated Mannich-Type Reaction of 2,2,2-Trifluorodiazoethane with Imines: Access to β-CF3-Amines.
A zinc-mediated Mannich-type transformation of 2,2,2-trifluorodiazoethane with a series of imines has been described. This method… Expand
2016
2016
Electrophilic Reaction of 2,2,2-Trifluorodiazoethane with the in Situ Generated N-Heterocyclic Carbenes: Access to N-Aminoguanidines.
A facile and efficient electrophilic reaction of 2,2,2-trifluorodiazoethane (CF3CHN2) with the in situ generated N-heterocyclic… Expand
Highly Cited
2015
Highly Cited
2015
Silver(I)-Catalyzed N-Trifluoroethylation of Anilines and O-Trifluoroethylation of Amides with 2,2,2-Trifluorodiazoethane.
A straightforward N-trifluoroethylation of anilines has been developed based on silver-catalyzed N-H insertions with 2,2,2… Expand
2015
2015
Silver-catalyzed regioselective [3+2] cycloaddition of arene-diazonium salts with 2,2,2-trifluorodiazoethane (CF3CHN2): a facile access to 2-aryl-5-trifluoromethyltetrazoles.
A silver-catalyzed regioselective [3+2] cycloaddition reaction of arenediazonium salts with 2,2,2-trifluorodiazoethane (CF3CHN2… Expand
2015
2015
Brine-Stabilized 2,2,2-Trifluorodiazoethane and Its Application in the Synthesis of CF3-Substituted Cyclopropane α-Amino Acids.
A facile thermodynamic cyclopropanation of trisubstituted olefinic azlactones with a stock solution of CF3CHN2 in CH3CN is… Expand
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Highly Cited
2014
Highly Cited
2014
Diastereoselective synthesis of vicinally bis(trifluoromethylated) alkylboron compounds through successive insertions of 2,2,2-trifluorodiazoethane.
The usefulness of embedded CF3 substituents within organic substructures necessitates the development of diverse methods for… Expand
Highly Cited
2014
Highly Cited
2014
Synthesis of CF3-containing 3,3'-cyclopropyl spirooxindoles by sequential [3 + 2] cycloaddition/ring contraction of ylideneoxindoles with 2,2,2-trifluorodiazoethane.
A [3 + 2] cycloaddition/ring contraction sequence of ylideneoxindoles with in situ-generated 2,2,2-trifluorodiazoethane without… Expand
2014
2014
A direct copper-promoted three-component entry to trifluoromethylketoximes.
A new copper-promoted three-component method for constructing ketoximes has been developed. This transformation can be achieved… Expand
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Highly Cited
2013
Highly Cited
2013
Silver-mediated cycloaddition of alkynes with CF3CHN2: highly regioselective synthesis of 3-trifluoromethylpyrazoles.
immense usefulness of 3-trifluoromethylpyrazole derivatives, efficient construction of the 3-trifluoromethylpyrazole framework… Expand
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Review
2012
Review
2012
A facile parallel synthesis of trifluoroethyl-substituted alkynes.
The physicochemical and biological properties of an organic compound are profoundly modified by the presence of fluorine… Expand
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