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1,4-cyclohexadiene

 
National Institutes of Health

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2 relations

Broader (2)

Cyclohexenescyclohexadiene

Papers overview

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2015
2015
Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid† †Electronic supplementary information (ESI) available: Experimental section; synthesis, characterization and…
Binding of two HOTf molecules to MnIV(O) species resulted in contrasting effects on the reactivities in oxygen atom transfer and… Expand
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Highly Cited
2013
Highly Cited
2013
A mononuclear non-heme manganese(IV)-oxo complex binding redox-inactive metal ions.
Redox-inactive metal ions play pivotal roles in regulating the reactivities of high-valent metal-oxo species in a variety of… Expand
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Highly Cited
2010
Highly Cited
2010
The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway.
[Fe(IV)(O)(TMG(3)tren)](2+) (1; TMG(3)tren = 1,1,1-tris{2-[N(2)-(1,1,3,3-tetramethylguanidino)]ethyl}amine) is a unique example… Expand
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Highly Cited
2008
Highly Cited
2008
A concise and flexible synthesis of the potent anti-influenza agents tamiflu and tamiphosphor.
We report safer and more commercially viable synthetic methods for both antiinfluenza drugs Tamiflu and Tamiphosphor using… Expand
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Highly Cited
2008
Highly Cited
2008
A two-state reactivity rationale for counterintuitive axial ligand effects on the C-H activation reactivity of nonheme FeIV=O oxidants.
This paper addresses the observation of counterintuitive reactivity patterns of iron-oxo reagents, TMC(L)FeO(2+,1+); L=CH(3)CN… Expand
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Highly Cited
2008
Highly Cited
2008
Reaction of phenols with the 2,2-diphenyl-1-picrylhydrazyl radical. Kinetics and DFT calculations applied to determine ArO-H bond dissociation enthalpies and reaction mechanism.
The formal H-atom abstraction by the 2,2-diphenyl-1-picrylhydrazyl (dpph(*)) radical from 27 phenols and two unsaturated… Expand
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Highly Cited
2005
Highly Cited
2005
A terminal Ni(III)-imide with diverse reactivity pathways.
The synthesis and structure of the beta-diketiminato Ni(I) lutidine adducts [MexNN]Ni(2,4-lutidine) (x = 2 (2); x = 3 (3)) are… Expand
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2000
2000
Linear free energy relationships in the Bergman cyclization of 4-substituted-1,2-diethynylbenzenes
Abstract A series of 4-substituted-1,2-diethylnylbenzenes were prepared ( 1a – f ) and subjected to Bergman cyclization. Bulk… Expand
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Highly Cited
1994
Highly Cited
1994
Synthesis of Polyphenylenes and Polynaphthalenes by Thermolysis of Enediynes and Dialkynylbenzenes
Abstract : Described are the syntheses of substituted enediynes and dialkynylbenzenes using Pd- or Pd/Cu-catalyzed cross coupling… Expand
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Highly Cited
1994
Highly Cited
1994
A Hypothetical Dense 3,4-Connected Carbon Net and Related B2C and CN2 Nets Built from 1,4-Cyclohexadienoid Units
This paper describes the geometrical and electronic structure of a hypothetical 3 ,4-co~ected tetragonal allotrope of carbon… Expand
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