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1,1,1-tris(hydroxymethyl)ethane

 
National Institutes of Health

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Alkanes

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2018
2018
Tuning the Condensation Degree of {FeIIIn} Oxo Clusters via Ligand Metathesis, Temperature, and Solvents.
Trinuclear μ3-oxo-centered iron(III) isobutyrate clusters readily react with polyalcohol organic ligands under one-pot synthesis… Expand
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2013
2013
Syntheses, structures and magnetic properties of a family of heterometallic [Mn(II)2Mn(III)2Ln(III)2] clusters.
A new family of isostructural Mn-Ln heterometallic clusters, [Mn(II)(2)Mn(III)(2)Ln(III)(2)(Piv)(8)(thme)(2)(H(2)tea)(2)] (H(3… Expand
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2011
2011
Transition-metal-free intramolecular Ullmann-type O-arylation: synthesis of chromone derivatives.
Aromatic C O bond-forming reactions are important in organic synthesis because these bonds occur in numerous natural products… Expand
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2010
2010
A variety of new tri- and tetranuclear Mn-Ln and Fe-Ln (Ln = lanthanide) complexes
Abstract The use of carboxylates in the synthesis of 3d/4f clusters, with or without a second organic ligand, has afforded a… Expand
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2009
2009
Fast Access to Dendrimer-like Poly(ethylene oxide)s through Anionic Ring-Opening Polymerization of Ethylene Oxide and Use of Nonprotected Glycidol as Branching Agent
Dendrimer-like poly(ethylene oxide)s (PEOs) were synthesized through a semicontinuous process based on the anionic ring-opening… Expand
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2008
2008
High-spin Mn4 and Mn10 molecules: large spin changes with structure in mixed-valence MnII4MnIII6 clusters with azide and alkoxide-based ligands.
The use has been explored of both azide (N3-) and alkoxide-containing groups such as the anions of 2-(hydroxymethyl)pyridine… Expand
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Highly Cited
2006
Highly Cited
2006
1,1,1-tris(hydroxymethyl)ethane as a new, efficient, and versatile tripod ligand for copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols.
1,1,1-tris(hydroxymethyl)ethane was presented as a new, efficient, and versatile tridentate O-donor ligand suitable for the… Expand
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2005
2005
Studies of an enneanuclear manganese single-molecule magnet.
The reaction of [Mn(3)O(O(2)CMe)(6)(py)(3)] with the tripodal ligand H(3)thme (1,1,1-tris(hydroxymethyl)ethane) affords the… Expand
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2004
2004
A family of manganese rods: syntheses, structures, and magnetic properties.
The reaction of the mixed-valent metal triangles [Mn(3)O(O(2)CR)(6)(py)(3)] (R = CH(3), Ph, C(CH(3))(3)) with the tripodal… Expand
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1996
1996
Metal Binding of Polyalcohols. 4. Structure and Magnetism of the Hexanuclear, &mgr;(6)-Oxo-Centered [OFe(6)(H(-)(3)thme)(3)(OCH(3))(3)Cl(6)](2)(-) (thme = 1,1,1-Tris(hydroxymethyl)ethane).
The addition of [N(CH(3))(4)]OH to a methanolic solution of FeCl(3) and thme (thme = 1,1,1-tris(hydroxymethyl)ethane) yielded [N… Expand
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