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(trifluoromethyl)-trimethylsilane

Known as: (trifluoromethyl)trimethylsilane, CF3SiMe3 
National Institutes of Health

Related topics

Related topics

2 relations

Broader (2)

Hydrocarbons, FluorinatedTrimethylsilyl Compounds

Papers overview

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Highly Cited
2017
Highly Cited
2017
CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3SO2Na
Sodium trifluoromethanesulfinate, CF3SO2Na, and trifluoromethanesulfonyl chloride, CF3SO2Cl, are two popular reagents that are… 
2017
2017
Stable (sila)difluoromethylboranes via C-F activation of fluoroform derivatives.
Lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-uide activates the C-F linkage of fluoroform (CF3H) and… 
Review
2014
Review
2014
Oxidative trifluoromethylation and trifluoromethylthiolation reactions using (trifluoromethyl)trimethylsilane as a nucleophilic CF3 source.
The trifluoromethyl group is widely prevalent in many pharmaceuticals and agrochemicals because its incorporation into drug… 
Highly Cited
2014
Highly Cited
2014
Copper-catalyzed synthesis of α-trifluoromethylthio-substituted ketones.
The CF3S-substituted moiety serves as an important structural element in many bioactive molecules. A versatile copper catalyst… 
Highly Cited
2013
Highly Cited
2013
Formation of C-SCF3 bonds through direct trifluoromethylthiolation.
For a long time, the SCF3 moiety has attracted the interest of chemists because of its intrinsic properties, including its high… 
Highly Cited
2013
Highly Cited
2013
Silver-catalyzed hydrotrifluoromethylation of unactivated alkenes with CF3SiMe3.
For the first time the title reaction is presented providing a wide range of trifluoromethylated alkanes. 
Highly Cited
2013
Highly Cited
2013
Sandmeyer trifluoromethylation of arenediazonium tetrafluoroborates.
The development of methods for the introduction of trifluoromethyl groups into functionalized molecules is of great importance… 
Highly Cited
2012
Highly Cited
2012
Copper-catalyzed oxidative trifluoromethylation of terminal alkenes using nucleophilic CF3SiMe3: efficient C(sp3)-CF3 bond formation.
An efficient C(sp(3))-CF(3) bond-forming reaction via Cu-catalyzed oxidative trifluoromethylation of terminal alkenes has been… 
Highly Cited
2012
Highly Cited
2012
Trifluoromethylation of allylsilanes under copper catalysis.
The trifluoromethylation reactions are performed with Togni reagent (II) to give branched allylic trifluoromethylated products. 
Highly Cited
2012
Highly Cited
2012
Oxidative trifluoromethylation of arylboronates with shelf-stable potassium (trifluoromethyl)trimethoxyborate.
With copper acetate as mediator and molecular oxygen as the oxidant, the reaction provides the trifluoromethylated products in… 
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