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(S)-ethyl 3-hydroxybutyrate

National Institutes of Health

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ethyl 3-hydroxybutyrate

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2014
2014
Utilization of whole cell mediated deracemization in a chemoenzymatic synthesis of enantiomerically enriched polycyclic chromeno[4,3-b] pyrrolidines.
Various aryl and alkyl substituted optically pure propargyl alcohols were obtained with excellent ee (up to >99%) and isolated… 
2014
2014
Catalyst-free three-component reaction to synthesize chiral α-amino phosphine oxides
A three-component reaction for high diastereoselective synthesis of chiral α-amino phosphine oxides has been developed and… 
Review
2012
Review
2012
Synthetic routes to chiral nonracemic and racemic dihydro- and tetrahydrothiophenes.
Natural and man-made organosulfur compounds play important roles in biological and medicinal chemistry. Among the various classes… 
2010
2010
Calorimetric Insight into Coupling between Functionalized Primary Alkyl Halide and Vinylic Organocuprate Reagent: Experimental Determination of Reaction Enthalpies in the Synthesis of (R)-Ethyl 3…
The first calorimetric study of coupling between organocuprate, derived from Grignard reagent (vinyl magnesium chloride), and… 
2008
2008
Improvements of enzyme activity and enantioselectivity via combined substrate engineering and covalent immobilization
Esterases, lipases, and serine proteases have been applied as versatile biocatalysts for preparing a variety of chiral compounds… 
2004
2004
Synthesis, theoretical and structural analyses, and enantiopharmacology of 3-carboxy homologs of AMPA.
We have previously used homologation of (S)-glutamic acid (Glu) and Glu analogs as an approach to the design of selective ligands… 
Highly Cited
2001
Highly Cited
2001
Evaluation of key aroma compounds in hand-squeezed grapefruit juice (Citrus paradisi Macfayden) by quantitation and flavor reconstitution experiments.
Twenty-five odor-active compounds were quantified in the fresh, hand-squeezed juice of White Marsh seedless grapefruits using… 
Highly Cited
2001
Highly Cited
2001
Evaluation of aroma differences between hand-squeezed juices from Valencia late and Navel oranges by quantitation of key odorants and flavor reconstitution experiments.
Twenty-five odor-active compounds were quantified in hand-squeezed juices of Valencia late and Navel oranges using stable isotope… 
2000
2000
Metabolism of ethyl tiglate in apple fruits leads to the formation of small amounts of (R)-ethyl 2-methylbutanoate.
(S)-Ethyl 2-methylbutanoate is an important aroma compound in apples and serves as an indicator for genuineness of apple products… 
1998
1998
Stereocontrolled Syntheses of Piperidine Derivatives Using Diastereoselective Reactions of Chiral 1,3-Oxazolidines with Grignard Reagents: Asymmetric Syntheses of the Pinidine Enantiomers.
Pinidine is the main constituent of Pinus sabiniana and related plant species as determined, along with its chemical structure… 
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