mer-[Fe(pcq)(CN)3]-: a novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion].

@article{Ni2005merFepcqCN3AN,
  title={mer-[Fe(pcq)(CN)3]-: a novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion].},
  author={Zhong-Hai Ni and Hui-Zhong Kou and Li-fang Zhang and Wei-Wei Ni and Yun-Bo Jiang and A L Cui and Joan Ribas and Osamu Sato},
  journal={Inorganic chemistry},
  year={2005},
  volume={44 26},
  pages={9631-3}
}
A new cyanide-containing building block K[Fe(pcq)(CN)(3)] [1; pcq(-) = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin Fe(III) center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear Fe(III)(2)Mn(II) complexes, [Fe(pcq)(CN)(3)](2)[Mn(CH(3)OH)(2)(H(2)O)(2… CONTINUE READING