iated nickel catalyzed C ( sp 3 ) – H thiocarbonylation of ethers †


The first direct C(sp)–H thiocarbonylation reaction is achieved by visible light photoredox/Ni dual catalysis. The thioester group of thiobenzoate is transferred to the a-oxy carbon of various cyclic/acyclic ethers, which is the opposite to the commonly expected chemical reactivity involving acyl group transfer via the weaker C(acyl)–S activation. Through… (More)

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