catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2 S:S]]


In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra-hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N-H⋯N hydrogen bonds generate layers in the ac plane. Weak intra-chain N-H⋯Br inter-actions also occur.

DOI: 10.1107/S1600536812014444

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@inproceedings{Saithong2012CS, title={ catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2 S:S]]}, author={Saowanit Saithong and Jonathan P. H. Charmant and Chaveng Pakawatchai}, booktitle={Acta crystallographica. Section E, Structure reports online}, year={2012} }