Zur Reaktivität von Natrium-bis-trimethylsilylamid gegenüber Metallcarbonylkomplexen mit Metall-Metall-Bindungen, I ER2-verbrückte Dicyano- und Diisonitril-octacarbonyl-dimanganate (E = Sn, Pb) / The Reactivity of Sodium Bis-trimethylsilylamide against Metal Carbonyl Complexes with Metal Metal Bonds

@article{Moll1986ZurRV,
  title={Zur Reaktivit{\"a}t von Natrium-bis-trimethylsilylamid gegen{\"u}ber Metallcarbonylkomplexen mit Metall-Metall-Bindungen, I ER2-verbr{\"u}ckte Dicyano- und Diisonitril-octacarbonyl-dimanganate (E = Sn, Pb) / The Reactivity of Sodium Bis-trimethylsilylamide against Metal Carbonyl Complexes with Metal Metal Bonds},
  author={Matthias Moll and Helmut Behrens and Peter Merbach and Karl-Heinz Tr{\"u}mmer and Gerhard Thiele and K. Wittmann},
  journal={Zeitschrift f{\"u}r Naturforschung B},
  year={1986},
  volume={41},
  pages={606 - 616}
}
Abstract EPh2 bridged dicyano octacarbonyl dimetalates {Ph2E[Mn(CO)4CN]2}2- are formed by the reaction of bis(carbonyl-metalates) of tin and lead Ph2E[Mn(CO)5]2 with NaN(SiMe3)2. The new dicyano anions can be transformed with trialkyloxonium tetrafluoroborates [R′3O]BF4 or chlor-trimethylsilane and -germane into the corresponding diisonitrile complexes Ph2E[Mn(CO)4CNR′]2 (R′=Me, Et, SiMe3, GeMe3). In the case of Ph2E [Mn(CO)4CNR′]2 (R′=Me, Et; E=Sn, Pb) the two phenyl groups can be removed with… Expand
6 Citations
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References

SHOWING 1-10 OF 11 REFERENCES
Adv
  • Organomet. Chem. 18, 1
  • 1980
P
  • Merbach und M. M oll, Z. Anorg. Allg. Chem. 456, 16
  • 1979
Y
  • Yoshikawa und H. Yamatera, J. Orga­ nomet. Chem. 157, 187
  • 1978
H
  • J. Haupt und F. Huber, Z. Anorg. Allg. Chem. 412, 77
  • 1975
W
  • W olfes und H. J. Haupt, Z. Anorg. Allg. Chem. 412, 121
  • 1975
(b)
W
  • Schubert und F. Huber, J. Organo­ met. Chem. 54, 231
  • 1973
L
  • H. Sutcliffe und B. Taylor, Spectro­ chim. Acta 2 8 A , 197
  • 1972
Oakridge National Laboratory, R e­ port 3794
  • Oakridge Tenn
  • 1965
Elian und R . Hoffmann
  • Allg . Chem .
...
1
2
...