Zur Reaktion von Hexamethyldistannoxan und Hexamethyldistannthian mit Phosphor-oxo- bzw. -thio-halogeniden. Schwingungsspektren von (Me2PS)2O und (Me2PS)2S / On the Reactions of Hexamethyldistannoxane and Hexamethyldistannthiane with Phosphorus-oxy and -thio-halides. Vibrational Spectra of (Me2PS)2O

@article{Shihada1984ZurRV,
  title={Zur Reaktion von Hexamethyldistannoxan und Hexamethyldistannthian mit Phosphor-oxo- bzw. -thio-halogeniden. Schwingungsspektren von (Me2PS)2O und (Me2PS)2S / On the Reactions of Hexamethyldistannoxane and Hexamethyldistannthiane with Phosphorus-oxy and -thio-halides. Vibrational Spectra of (Me2PS)2O},
  author={A. F. Shihada and Ihsan A. M. Jasim},
  journal={Zeitschrift f{\"u}r Naturforschung B},
  year={1984},
  volume={39},
  pages={783 - 787}
}
M e3S n 0 2PCl2 and (M e2PS)20 are prepared from the reactions of (M e3Sn)20 with POCl3 (1:1) and with M e2PSCl (1:2), respectively. The reactions of (M e3Sn)2S with M e2PSCl and with PSBr3 lead to the formation of (M e2PS)2S and P4S9, respectively. POCl3 reacts with (M e3Sn)2S to give unidentified products as a result of O/S exchange. The i.r. and Raman spectra o f the solids (M e2PS)20 and (M e2PS)2S and the Raman spectra of the molten compounds are reported and the frequencies assigned.