Zirconium-substituted isopolytungstates: structural models for zirconia-supported tungsten catalysts.

Abstract

The synthesis and characterization of a series of mixed W-Zr polynuclear Lindqvist-type complexes, deriving from hexatungstate [W6O19]2-, are described in this work. This family of compounds is built from {W5O18Zr}2- moieties as shown by the X-ray structures of the monomeric [W5O18Zr(H2O)(3-n)(DMSO)n]2- (n = 1 and 2) and dimeric [{W5O18Zr(mu-OH)}2]6- anions… (More)

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Cite this paper

@article{Carabineiro2006ZirconiumsubstitutedIS, title={Zirconium-substituted isopolytungstates: structural models for zirconia-supported tungsten catalysts.}, author={Hugo Carabineiro and Richard Villanneau and Xavier Carrier and Patrick Herson and Francisco Manuel da Silva Lemos and Fernando Ram{\^o}a Ribeiro and Anna Proust and Michel Che}, journal={Inorganic chemistry}, year={2006}, volume={45 5}, pages={1915-23} }