Zirconium-metalloporphyrin frameworks as a three-in-one platform possessing oxygen nanocage, electron media, and bonding site for electrochemiluminescence protein kinase activity assay.

@article{Zhang2016ZirconiummetalloporphyrinFA,
  title={Zirconium-metalloporphyrin frameworks as a three-in-one platform possessing oxygen nanocage, electron media, and bonding site for electrochemiluminescence protein kinase activity assay.},
  author={Guang-Yao Zhang and Chang Cai and Serge Cosnier and Haibo Zeng and Xue-ji Zhang and Dan Shan},
  journal={Nanoscale},
  year={2016},
  volume={8 22},
  pages={
          11649-57
        }
}
A Zr-based metal-organic framework with zinc tetrakis(carboxyphenyl)-porphyrin (ZnTCPP) groups (MOF-525-Zn) was utilized to develop a novel electrochemiluminescence (ECL) biosensor for highly sensitive protein kinase activity assay. In this work, in terms of ECL measurements and cyclic voltammetry, the cathodic ECL behaviors of MOF-525-Zn in aqueous media were thoroughly investigated for the first time. The photoelectric active groups ZnTCPP on the MOF-525-Zn frameworks could promote the… CONTINUE READING

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