XIX. On a new series of organic bodies containing metals
@article{FranklandXIXOA,
title={XIX. On a new series of organic bodies containing metals},
author={Edward Percy Frankland},
journal={Philosophical Transactions of the Royal Society of London},
pages={417 - 444}
}Under the above title I described, more than three years ago, some preliminary experiments which proved the existence of certain organic compounds highly analogous to cacodyl, and, like that body, consisting of a metal, or in some cases phosphorus, associated with the groups C2 H3, C4 H5, C6 H7, &c., and possessing, in most instances, highly remarkable powers of combination. I fixed the composition and studied some of the reactions of two of these bodies, to which the names Zincmethyl (C2 H3 Zn… Expand
7 Citations
Caminhos preparatórios de Lewis e seu interesse pelas ligações químicas
- Sociology
- 2020
In order to guide the reader in the context of the elaboration of Gilbert Newton Lewis’s shared pair theory (1875-1946), we focus on the original documents published by him and the available… Expand
Roby-Gould bond indices as a tool for understanding chemical bonding from a mathematical and quantum mechanical perspective
- Physics
- 2020
Abstract In this paper we elaborate and evaluate the Roby-Gould bond index method (RGBI) for classifying and interpreting the nature of chemical bonds [Gould et al., Theor. Chem. Acc., 2008, 119,… Expand
Evolution towards green radical generation in total synthesis.
- Medicine
- Chemical Society reviews
- 2021
The use of radicals as intermediates in total synthesis has evolved since their initial use in the latter half of the twentieth century. Radical generation from metal hydride methodologies has… Expand
Before Radicals Were Free – the Radical Particulier of de Morveau
- Chemistry
- 2020
Today, we universally understand radicals to be chemical species with an unpaired electron. It was not always so, and this article traces the evolution of the term radical and in this journey,… Expand
What's in a Name?—A Short History of Coordination Chemistry from Then to Now
- Chemistry
- Chemistry
- 2019
This article traces the development of coordination chemistry and shows how progress in the science has been paralleled by the development of a vocabulary and nomenclature to describe new concepts,… Expand
Chemical Bonding: The Journey from Miniature Hooks to Density Functional Theory
- Medicine
- Molecules
- 2020
This review article traces the development of the understanding of bonding from prehistory, through the debates in the 19th century C.E. bearing on valence, to modern quantum chemical models and beyond. Expand
Static to Dynamic: Kazan Chemists and the Transformation from Chemical Structure to Reaction Regiochemistry.
- Medicine, Chemistry
- Angewandte Chemie
- 2019
During the sesquicentennial of the first publication of Markovnikov's Rule, it is appropriate to re-visit the development of A. M. Butlerov's version of the theory of chemical structure, and its… Expand