X-Ray crystal structure of [HSm{V(IV)O(TPPS)}]n and encapsulation of nitrogen molecules in 1-D channels.

Abstract

The crystal structure of an N(2)-encapusulated MOF, which is stable under open-air conditions at ambient temperature, was determined by single-crystal X-ray diffraction at 123 K. The crystal MOF of [HSm{V(IV)O(TPPS)}](n) designed to have 1-D channels periodically constricted by porphyrins planes adsorbed N(2) at 77 K. The adsorbed N(2) molecules remained in… (More)
DOI: 10.1039/c1dt10956a

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