Corpus ID: 76653180

Wheels and Vertex-shared Spirocyclic Ln 5 Cores : Synthesis , Structure , SMM Behavior and MCE Properties

@inproceedings{Das2017WheelsAV,
  title={Wheels and Vertex-shared Spirocyclic Ln 5 Cores : Synthesis , Structure , SMM Behavior and MCE Properties},
  author={Sourav Das and Atanu Dey and Subrata Kundu and S. Biswas and Ramakirushnan Suriya and Narayanan and Silvia Titos-Padilla and G. Lorusso and M. Evangelisti and E. Colacio and V. Chandrasekhar},
  year={2017}
}
  • Sourav Das, Atanu Dey, +8 authors V. Chandrasekhar
  • Published 2017
  • The reaction of a Schiff-base ligand (LH3) with lanthanide salts, pivalic acid and triethylamine in 1:1:1:3 and 4:5:8:20 stoichiometric ratios results in the formation of decanuclear Ln10 [Ln= Dy(1), Tb(2) and Gd(3)] and pentanuclear Ln5 complexes [Ln= Gd(4), Tb(5) and Dy(6)] respectively. The formation of Ln10 and Ln5 complexes are fully governed by the stoichiometry of the reagents used. Detailed magnetic studies on these complexes (1-6) have been carried out. Complex 1 shows a SMM behavior… CONTINUE READING

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