Water oxidation by lambda-MnO2: catalysis by the cubical Mn4O4 subcluster obtained by delithiation of spinel LiMn2O4.

Abstract

Nanocrystalline spinel LiMn(2)O(4) has been prepared and treatment of LiMn(2)O(4) with dilute nitric acid solution resulted in the delithiation of the framework, while maintaining the spinel structure, lambda-MnO(2). LiMn(2)O(4) is not a catalyst for water oxidation. Upon removal of the lithium, the cubical Mn(4)O(4) cores become active sites for oxidizing… (More)
DOI: 10.1021/ja1055615

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