Water molecule induced reversible single-crystal-to-single-crystal transformation between two trinuclear Fe(ii) complexes with different spin crossover behaviour.

@article{Chen2018WaterMI,
  title={Water molecule induced reversible single-crystal-to-single-crystal transformation between two trinuclear Fe(ii) complexes with different spin crossover behaviour.},
  author={Wen-Bin Chen and Yan-Cong Chen and Meng Yang and Ming‐Liang Tong and Wen Dong},
  journal={Dalton transactions},
  year={2018},
  volume={47 12},
  pages={
          4307-4314
        }
}
A 4-amino-1,2,4-triazole (NH2-trz) based linear trinuclear Fe(ii) complex of [Fe3(NH2-trz)6(SCN)4(H2O)2](SCN)2·H2O (1) has been hydrothermally synthesized by the reaction of a NH2-trz ligand with FeSO4. A single crystal of complex 1 is able to extrude one lattice water and one coordinated water, leading to another single crystal of complex 1a with a formula [Fe3(NH2-trz)6(SCN)5(H2O)](SCN) by heating. Complex 1a can be reversed to 1 upon the reabsorption of water. Single-crystal X-ray… 
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16 Citations

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