Volume Correction for Bead Model Simulations of Rotational Friction Coefficients of Macromolecules

@inproceedings{Antosiewicz2001VolumeCF,
title={Volume Correction for Bead Model Simulations of Rotational Friction Coefficients of Macromolecules},
author={Jan M Antosiewicz and Dietmar Porschke},
year={2001}
}

In order to obtain an optimal representation of the experimental spectra by the theoretical spectra in Figure 9, the diffusion coefficient D also was taken as an adjustable parameter. Clearly, we would expect D to be independent of the electrical field E. In Figure 1 1, we show the fitted diffusion coefficients D as a function of the applied field, which are definitely not independent of E . It is interesting to note, however, that with vanishing field E the diffusion coefficient extrapolates… CONTINUE READING