Visible light-driven O2 reduction by a porphyrin-laccase system.


Several recent studies have shown that the combination of photosensitizers with metalloenzymes can support a light-driven multielectron reduction of molecules such as CO(2) or HCN. Here we show that the association of the zinc tetramethylpyridinium porphyrin (ZnTMPyP(4+)) photosensitizer with the multicopper oxidase (MCO) laccase allows to link the… (More)
DOI: 10.1021/ja309969s


7 Figures and Tables