Vibrational relaxation of matrix-isolated CH/sub 3/F and HCl

  title={Vibrational relaxation of matrix-isolated CH/sub 3/F and HCl},
  author={Linda Wai Ling Young},
Kinetic and spectroscopic studies have been performed on CH/sub 3/F and HCl as a function of host matrix and temperature. Temporally and spectrally resolved infrared fluorescence was used to monitor the populations of both the initially excited state and the lower lying levels which participate in the relaxation process. For CH/sub 3/F, relaxation from any of the levels near 3.5, i.e. the CH stretching fundamentals or bend overtones, occurs via rapid ( .. V transfer to 3… CONTINUE READING