Corpus ID: 235436187

Vibrational relaxation of hot ground state cations of naphthalene

@inproceedings{Reitsma2021VibrationalRO,
  title={Vibrational relaxation of hot ground state cations of naphthalene},
  author={G. Reitsma and S. Patchkovskii and J. Dur{\'a} and L. Drescher and J. Mikosch and M. Vrakking and O. Kornilov},
  year={2021}
}
Time-resolved XUV-IR photoion mass spectroscopy of naphthalene conducted with broadband, as well as with wavelength-selected narrowband XUV pulses reveals a rising probability of fragmentation characterized by a lifetime of 92 ± 4 fs. This lifetime is independent of the XUV excitation wavelength and is the same for all low appearance energy fragments recorded in the experiment. Analysis of the experimental data in conjunction with a statistical multi-state vibronic model suggests that the… Expand

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