Vibrational relaxation of NO on Au(111) via electron-hole pair generation.

@article{Shenvi2006VibrationalRO,
  title={Vibrational relaxation of NO on Au(111) via electron-hole pair generation.},
  author={Neil A Shenvi and Sharani Roy and Priya V Parandekar and John C. Tully},
  journal={The Journal of chemical physics},
  year={2006},
  volume={125 15},
  pages={154703}
}
Recent experiments have demonstrated the breakdown of the Born-Oppenheimer approximation when NO undergoes inelastic scattering from a Au(111) surface. In this paper, we provide a simple theoretical model for understanding this phenomenon. Our model predicts multiquanta vibrational relaxation through the creation of high-energy electron-hole pair excitations in the metal. Using experimentally determined parameters, our model gives qualitatively accurate predictions for the final vibrational… CONTINUE READING

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